Synthesis of magnesium ZIF-8 from Mg(BH4)2

被引：33

作者：

Horike, S. ^{[1
,2
]}

Kadota, K. ^{[1
]}

Itakura, T. ^{[3
]}

Inukai, M. ^{[4
]}

Kitagawa, S. ^{[1
,4
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[2] Japan Sci & Technol Agcy, PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] DENSO Corp, Kariya, Aichi 4488661, Japan

[4] Kyoto Univ, Inst Integrated Cell Mat Sci WPI iCeMS, Sakyo Ku, Kyoto 6068501, Japan

来源：

DALTON TRANSACTIONS | 2015年 / 44卷 / 34期

基金：

日本科学技术振兴机构;

关键词：

METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; THERMAL-STABILITY; SURFACE-AREA; COMPLEX;

D O I：

10.1039/c5dt01183c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Porous Mg(2-methyl imidazolate)(2) (Mg-ZIF-8) was synthesised from Mg(BH4)(2) as a precursor under an Ar atmosphere. It possesses an uncommon tetrahedral Mg2+-N coordination geometry that is stabilised by the formation of a framework, and it exhibits a Brunauer-Emmett-Teller surface area greater than 1800 m(2) g(-1).

引用

页码：15107 / 15110

页数：4

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