Synthesis of Manganese ZIF-8 from [Mn(BH4)2•3THF]•NaBH4

被引：42
|
作者：
Kadota, Kentaro [1 ]
Sivaniah, Easan [1 ,3 ]
Bureekaew, Sareeya [4 ]
Kitagawa, Susumu [3 ]
Horike, Satoshi [2 ,3 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan
[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan
[3] Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci WPI iCeMS, Kyoto 6068501, Japan
[4] Vidyasirimedhi Inst Sci & Technol, Sch Energy Sci & Engn, Dept Chem & Biomol Engn, Rayong 21210, Thailand
来源：
INORGANIC CHEMISTRY | 2017年 / 56卷 / 15期
基金：
日本科学技术振兴机构; 日本学术振兴会;
关键词：
METAL-ORGANIC FRAMEWORKS; IMIDAZOLATE FRAMEWORKS; CRYSTAL-STRUCTURES; THERMAL-STABILITY; SURFACE; COMPLEXES; CATALYSIS; DESIGN;
D O I：
10.1021/acs.inorgchem.7b01322
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Cubic and highly porous [Mn(2-methyl-imidazolate)(2)] (Mn-ZIF-8) was synthesized from [Mn-(BH4)(2)center dot 3THF]center dot NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger amounts of gas uptake compared with [Zn(2-methylimidazolate)(2)]. A kinetically favored reaction using a reactive metal borohydride precursor is key for the construction of new metal organic framework systems.
引用
收藏
页码：8744 / 8747
页数：4
相关论文
共 50 条
  • [41] Enhanced hydrogen storage properties of NaBH4-Mg(BH4)2 composites by NdF3 addition
    Yuan, Jianguang
    Chen, Jinting
    Huang, Haixiang
    Lv, Yujie
    Liu, Bogu
    Li, Zhongyu
    Zhang, Bao
    Lv, Wei
    Wu, Ying
    PROGRESS IN NATURAL SCIENCE-MATERIALS INTERNATIONAL, 2021, 31 (04) : 521 - 526
  • [42] Ex situ characterization of N2H4-, NaBH4- and NH3BH3- reduced cobalt catalysts used in NaBH4 hydrolysis
    Cavaliere, S.
    Hannauer, J.
    Demirci, U. B.
    Akdim, O.
    Miele, P.
    CATALYSIS TODAY, 2011, 170 (01) : 3 - 12
  • [43] AZn2(BH4)5 (A = Li, Na) and NaZn(BH4)3: Structural Studies
    Cerny, Radovan
    Kim, Ki Chul
    Penin, Nicolas
    D'Anna, Vincenza
    Hagemann, Hans
    Sholl, David S.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2010, 114 (44): : 19127 - 19133
  • [44] THE NABH4-LA(BH4)3-TETRAHYDROFURAN SYSTEM AT 25-DEGREES-C
    MIRSAIDOV, U
    KURBONBEKOV, A
    KHIKMATOV, M
    ZHURNAL NEORGANICHESKOI KHIMII, 1981, 26 (10): : 2875 - 2876
  • [45] Theoretical Study of Metal-Tetrahydroborato Ligand Interactions in [Y(THF)4(BH4)2]+
    Inorg Chem, 13 (3964):
  • [46] Theoretical study of metal-tetrahydroborato ligand interactions in [Y(THF)(4)(BH4)2](+)
    Xu, ZT
    Lin, ZY
    INORGANIC CHEMISTRY, 1996, 35 (13) : 3964 - 3966
  • [47] Syntheses and crystal structures of Ln(BH4)3(THF)3(Ln = Yb, Er)
    Yuan, FG
    Ying, T
    Hui, Q
    JOURNAL OF RARE EARTHS, 2005, 23 : 547 - 550
  • [48] Syntheses and Crystal Structures of Ln(BH4)3(THF)3 (Ln=Yb, Er)
    袁福根
    唐英
    钱蕙
    JournalofRareEarths, 2005, (S1) : 547 - 550
  • [49] Synthesis and crystal structure of gallosilicate- and aluminogermanate tetrahydroborate sodalites Na8[GaSiO4]6(BH4)2 and Na8[AlGeO4]6(BH4)2
    Buhl, Josef-C.
    Gesing, Thorsten M.
    Hoefs, Tanja
    Ruescher, Claus H.
    JOURNAL OF SOLID STATE CHEMISTRY, 2006, 179 (12) : 3877 - 3882
  • [50] Preparation and crystal structure of the neodymium borohydride [Li(thf)4]2[Nd2(μ-Cl)2(BH4)6(thf)2]
    Klein, Axel
    Pohl, Roland W. H.
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2008, 634 (08): : 1388 - 1392
12345