Synthesis of Manganese ZIF-8 from [Mn(BH4)2•3THF]•NaBH4

被引：42

作者：

Kadota, Kentaro ^{[1
]}

Sivaniah, Easan ^{[1
,3
]}

Bureekaew, Sareeya ^{[4
]}

Kitagawa, Susumu ^{[3
]}

Horike, Satoshi ^{[2
,3
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Mol Engn, Nishikyo Ku, Kyoto 6158510, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

[3] Kyoto Univ, Inst Adv Study, Inst Integrated Cell Mat Sci WPI iCeMS, Kyoto 6068501, Japan

[4] Vidyasirimedhi Inst Sci & Technol, Sch Energy Sci & Engn, Dept Chem & Biomol Engn, Rayong 21210, Thailand

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 15期

基金：

日本科学技术振兴机构; 日本学术振兴会;

关键词：

METAL-ORGANIC FRAMEWORKS; IMIDAZOLATE FRAMEWORKS; CRYSTAL-STRUCTURES; THERMAL-STABILITY; SURFACE; COMPLEXES; CATALYSIS; DESIGN;

D O I：

10.1021/acs.inorgchem.7b01322

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cubic and highly porous [Mn(2-methyl-imidazolate)(2)] (Mn-ZIF-8) was synthesized from [Mn-(BH4)(2)center dot 3THF]center dot NaBH4 under an Ar atmosphere. The structure contains rare Mn2+-4N tetrahedral geometry and has larger cell parameters, resulting in 20% larger amounts of gas uptake compared with [Zn(2-methylimidazolate)(2)]. A kinetically favored reaction using a reactive metal borohydride precursor is key for the construction of new metal organic framework systems.

引用

页码：8744 / 8747

页数：4

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