One-pot synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines using supported gold and base as catalysts

被引:83
|
作者
Kegns, Soren [1 ]
Mielby, Jerrik [1 ]
Mentzel, Uffe V. [1 ]
Jensen, Thomas [1 ]
Fristrup, Peter [1 ]
Riisager, Anders [1 ]
机构
[1] Tech Univ Denmark, Dept Chem, Ctr Catalysis & Sustainable Chem, DK-2800 Lyngby, Denmark
关键词
LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; SOLVATION; ENERGIES; WATER; MECHANICS; HYDROGEN; IMINES; CARBON;
D O I
10.1039/c2cc16768a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines via intermediate formation of methyl esters is highly efficient and selective when using a catalytic system comprised of supported gold nanoparticles and added base in methanol.
引用
收藏
页码:2427 / 2429
页数:3
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