One-pot synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines using supported gold and base as catalysts

被引：83

作者：

Kegns, Soren ^{[1
]}

Mielby, Jerrik ^{[1
]}

Mentzel, Uffe V. ^{[1
]}

Jensen, Thomas ^{[1
]}

Fristrup, Peter ^{[1
]}

Riisager, Anders ^{[1
]}

机构：

[1] Tech Univ Denmark, Dept Chem, Ctr Catalysis & Sustainable Chem, DK-2800 Lyngby, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 18期

关键词：

LIQUID-PHASE OXIDATION; SELECTIVE OXIDATION; MOLECULAR-OXYGEN; SOLVATION; ENERGIES; WATER; MECHANICS; HYDROGEN; IMINES; CARBON;

D O I：

10.1039/c2cc16768a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Synthesis of amides by aerobic oxidative coupling of alcohols or aldehydes with amines via intermediate formation of methyl esters is highly efficient and selective when using a catalytic system comprised of supported gold nanoparticles and added base in methanol.

引用

页码：2427 / 2429

页数：3

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