SU-16: A three-dimensional open-framework borogermanate with a novel zeolite topology

被引：78

作者：

Li, YF ^{[1
]}

Zou, XD ^{[1
]}

机构：

[1] Univ Stockholm, Arrhenius Lab, S-10691 Stockholm, Sweden

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 13期

关键词：

boron; germanium; hydrothermal synthesis; zeolite analogues;

D O I：

10.1002/anie.200461911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new secondary building unit with edge-sharing 3-rings of BO4 and GeO4 tetrahedra (shown in the picture in turquoise and yellow, respectively) forms the basis of the framework of SU-16, a borogermanate with zeolite topology. SU-16 has three-dimensional intersecting 12-ring and 8-ring channels. In particular the unusual elliptical 12-ring channels may make this zeolite structure interesting for shape selectivity. (Chemical Equation Presented). © 2005 Wiley-VCH Verlag GmbH S. Co. KGaA.

引用

页码：2012 / 2015

页数：4

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