A Three-Dimensional Open-Framework Tin(II) Sulfate with Near-Unity Photoluminescence Quantum Yield

被引：1
|
作者：
Wen, Xuemei [1 ]
Wang, Jing [1 ]
Zhang, Zhizhuan [1 ]
Han, Xiangyu [1 ]
Zeng, Hongmei [1 ]
Zou, Guohong [1 ]
Xu, Dingguo [1 ]
Lin, Zhien [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Chengdu 610064, Peoples R China
来源：
INORGANIC CHEMISTRY | 2024年 / 63卷 / 19期
基金：
中国国家自然科学基金;
关键词：
WHITE-LIGHT; ZINC PHOSPHATE; ZEOLITE; ALUMINOBORATE; EMISSION;
D O I：
10.1021/acs.inorgchem.4c00943
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new open-framework tin(II) sulfate, formulated as C4H12N2<middle dot>Sn(SO4)(2)<middle dot>H2O, was prepared under the structure-directing effect of piperazine. This compound features a 3D structure with 16-ring channels. Under ultraviolet light irradiation, it emits bright yellow luminescence with a near-unity photoluminescence quantum yield. Theoretical calculations were carried out to understand the luminescence mechanism.
引用
收藏
页码：8521 / 8525
页数：5
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