SU-16: A three-dimensional open-framework borogermanate with a novel zeolite topology

被引：78
|
作者：
Li, YF [1 ]
Zou, XD [1 ]
机构：
[1] Univ Stockholm, Arrhenius Lab, S-10691 Stockholm, Sweden
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 13期
关键词：
boron; germanium; hydrothermal synthesis; zeolite analogues;
D O I：
10.1002/anie.200461911
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new secondary building unit with edge-sharing 3-rings of BO4 and GeO4 tetrahedra (shown in the picture in turquoise and yellow, respectively) forms the basis of the framework of SU-16, a borogermanate with zeolite topology. SU-16 has three-dimensional intersecting 12-ring and 8-ring channels. In particular the unusual elliptical 12-ring channels may make this zeolite structure interesting for shape selectivity. (Chemical Equation Presented). © 2005 Wiley-VCH Verlag GmbH S. Co. KGaA.
引用
收藏
页码：2012 / 2015
页数：4
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