Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals

被引：8

作者：

Angeloski, Alexander ^{[1
]}

Cortie, Michael B. ^{[1
]}

Scott, John A. ^{[1
]}

Bordin, Dayanne M. ^{[1
]}

McDonagh, Andrew M. ^{[1
]}

机构：

[1] Univ Technol Sydney, Sch Math & Phys Sci, Ultimo 2007, Australia

来源：

INORGANICA CHIMICA ACTA | 2019年 / 487卷

关键词：

Dithiocarbamate; Nickel; Thermolysis; HIGH-PERFORMANCE SUPERCAPACITORS; THIN-FILMS; ELECTROCHEMICAL PERFORMANCE; COUNTER ELECTRODES; VAPOR-DEPOSITION; HOLLOW SPHERES; BETA-NIS; PHASE; NANOPARTICLES; COMPOSITES;

D O I：

10.1016/j.ica.2018.12.014

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Single crystals of bis(kappa S-2,S'-di(isopropyl)dithiocarbamato) nickel(II) were utilized as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at - 250 degrees C to form alpha-NiS exclusively with no beta-NiS detected. Analysis of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and carbon disulfide. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relationships.

引用

页码：228 / 233

页数：6

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