Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals

被引：8
|
作者：
Angeloski, Alexander [1 ]
Cortie, Michael B. [1 ]
Scott, John A. [1 ]
Bordin, Dayanne M. [1 ]
McDonagh, Andrew M. [1 ]
机构：
[1] Univ Technol Sydney, Sch Math & Phys Sci, Ultimo 2007, Australia
来源：
INORGANICA CHIMICA ACTA | 2019年 / 487卷
关键词：
Dithiocarbamate; Nickel; Thermolysis; HIGH-PERFORMANCE SUPERCAPACITORS; THIN-FILMS; ELECTROCHEMICAL PERFORMANCE; COUNTER ELECTRODES; VAPOR-DEPOSITION; HOLLOW SPHERES; BETA-NIS; PHASE; NANOPARTICLES; COMPOSITES;
D O I：
10.1016/j.ica.2018.12.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of bis(kappa S-2,S'-di(isopropyl)dithiocarbamato) nickel(II) were utilized as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at - 250 degrees C to form alpha-NiS exclusively with no beta-NiS detected. Analysis of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and carbon disulfide. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relationships.
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页码：228 / 233
页数：6
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