Conversion of single crystals of a nickel(II) dithiocarbamate complex to nickel sulfide crystals

被引：8
|
作者：
Angeloski, Alexander [1 ]
Cortie, Michael B. [1 ]
Scott, John A. [1 ]
Bordin, Dayanne M. [1 ]
McDonagh, Andrew M. [1 ]
机构：
[1] Univ Technol Sydney, Sch Math & Phys Sci, Ultimo 2007, Australia
来源：
INORGANICA CHIMICA ACTA | 2019年 / 487卷
关键词：
Dithiocarbamate; Nickel; Thermolysis; HIGH-PERFORMANCE SUPERCAPACITORS; THIN-FILMS; ELECTROCHEMICAL PERFORMANCE; COUNTER ELECTRODES; VAPOR-DEPOSITION; HOLLOW SPHERES; BETA-NIS; PHASE; NANOPARTICLES; COMPOSITES;
D O I：
10.1016/j.ica.2018.12.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Single crystals of bis(kappa S-2,S'-di(isopropyl)dithiocarbamato) nickel(II) were utilized as a single source precursor for the formation of NiS via thermolysis. The complex decomposed at - 250 degrees C to form alpha-NiS exclusively with no beta-NiS detected. Analysis of the thermolysis regime using in situ techniques showed that the thermolysis occurs in a single step with the major volatile side-products being isopropyl-isothiocyanate and carbon disulfide. The resultant NiS was examined using SEM and TEM to reveal a retention of precursor crystal edge-length and angle relationships.
引用
收藏
页码：228 / 233
页数：6
相关论文
共 50 条
  • [31] MAGNETOSTRICTION OF SINGLE CRYSTALS OF COBALT AND NICKEL FERRITES
    BOZORTH, RM
    WALKER, JG
    PHYSICAL REVIEW, 1952, 88 (05): : 1209 - 1209
  • [32] ORIENTATION EFFECT OF NICKEL SINGLE CRYSTALS ON MICROHARDNESS
    LAVECCHI.A
    NICODEMI, W
    METALLURGIA ITALIANA, 1965, 57 (09): : 321 - &
  • [33] Transformations of the Dislocation Structure of Nickel Single Crystals
    Alfyorova, E. A.
    Lychagin, D. V.
    Lychagina, L. L.
    Tsvetkov, N. A.
    PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS WITH HIERARCHICAL STRUCTURE FOR NEW TECHNOLOGIES AND RELIABLE STRUCTURES 2017 (AMHS'17), 2017, 1909
  • [34] Joining of nickel base superalloy single crystals
    Babu, SS
    David, SA
    Park, JW
    Vitek, JM
    SCIENCE AND TECHNOLOGY OF WELDING AND JOINING, 2004, 9 (01) : 1 - 12
  • [35] Welding of nickel base superalloy single crystals
    David, SA
    Vitek, JM
    Babu, SS
    Boatner, LA
    Reed, RW
    SCIENCE AND TECHNOLOGY OF WELDING AND JOINING, 1997, 2 (02) : 79 - 88
  • [36] SEMICONDUCTOR PROPERTIES OF SINGLE CRYSTALS OF NICKEL OXIDE
    KSENDZOV, YM
    AVDEENKO, BK
    MAKAROV, VV
    SOVIET PHYSICS SOLID STATE,USSR, 1967, 9 (04): : 828 - +
  • [37] Elastic properties of single crystals of nickel alloys
    Krivko, A.I.
    Epishin, A.I.
    Svetlov, I.L.
    Samoilov, A.I.
    Strength of materials, 1988, : 214 - 223
  • [38] OXIDE FORMATION AND REDUCTION ON SINGLE CRYSTALS OF NICKEL
    WEININGER, JL
    BREITER, MW
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1962, 109 (08) : C196 - C196
  • [39] The magnetic anisotropy of single crystals of iron and nickel
    Schlechtweg, I
    ANNALEN DER PHYSIK, 1936, 27 (07) : 573 - 596
  • [40] Recrystallization in single crystals of nickel base superalloys
    Bürgel, R
    Portella, PD
    Preuhs, J
    SUPERALLOYS 2000, 2000, : 229 - 238
12345