Dynamics of oxidation Belousov-Zhabotinsky waves in an electric field?

被引:42
|
作者
Sevcikova, H [1 ]
Schreiber, I [1 ]
Marek, M [1 ]
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT CHEM ENGN,CR-16628 PRAGUE 6,CZECH REPUBLIC
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期
关键词
D O I
10.1021/jp961789w
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experiments with oxidation circular waves in a quasi-two-dimensional Belousov-Zhabotinsky reaction medium subject to an external de electric field reveal a variety of wave dynamics scenarios involving wave splitting, reversal, annihilation, and complex pattern formation. We also investigate effects of initial concentration of reactants on the wave dynamics and find marked sensitivity related to excitability of the reaction medium. Two different variants of the Oregonator model are shown to have a common dimensionless representation providing conversion relations between corresponding rate coefficients. Modeling of the waves in an electric field is in qualitative agreement with experiments and predicts a rich structure of complex wave dynamics.
引用
收藏
页码:19153 / 19164
页数:12
相关论文
共 50 条
  • [31] Instability of the Homogeneous Distribution of Chemical Waves in the Belousov-Zhabotinsky Reaction
    Suematsu, Nobuhiko J.
    Nakata, Satoshi
    MATERIALS, 2021, 14 (20)
  • [32] THE MOTION OF UNTWISTED UNTORTED SCROLL WAVES IN BELOUSOV-ZHABOTINSKY REAGENT
    KEENER, JP
    TYSON, JJ
    SCIENCE, 1988, 239 (4845) : 1284 - 1286
  • [33] ENTRAINMENT OF SPIRAL WAVES BY EXTERNAL FORCING OF THE BELOUSOV-ZHABOTINSKY REACTION
    STEINBOCK, O
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 233 - PHYS
  • [34] On the Origin of the Belousov-Zhabotinsky Reaction
    Pechenkin A.
    Biological Theory, 2009, 4 (2) : 196 - 206
  • [35] Chaos in the Belousov-Zhabotinsky reaction
    Field, Richard J.
    MODERN PHYSICS LETTERS B, 2015, 29 (34):
  • [36] Spiral breakup induced by an electric current in a Belousov-Zhabotinsky medium
    Taboada, J. J.
    Munuzuri, A. P.
    Perez-Munuzuri, V.
    Gomez-Gesteira, M.
    Perez-Villar, V.
    CHAOS, 1994, 4 (03) : 519 - 524
  • [37] Effect of inhomogeneities on spiral wave dynamics in the Belousov-Zhabotinsky reaction
    Smolka, LB
    Marts, B
    Lin, AL
    PHYSICAL REVIEW E, 2005, 72 (05):
  • [38] Period-doubling geometry of the Belousov-Zhabotinsky reaction dynamics
    Wang, JC
    Hynne, F
    Sorensen, PG
    INTERNATIONAL JOURNAL OF BIFURCATION AND CHAOS, 1996, 6 (07): : 1267 - 1279
  • [39] DYNAMICS OF CONVECTIVE INSTABILITY OF WAVES IN THE BELOUSOV-ZHABOTINSKY REACTION AS MEASURED BY MAGNETIC-RESONANCE-IMAGING
    MENZINGER, M
    TZALMONA, A
    ARMSTRONG, RL
    CROSS, A
    LEMAIRE, C
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (12): : 4725 - 4727
  • [40] Front dynamics in an oscillatory bistable Belousov-Zhabotinsky chemical reaction
    Marts, B
    Martinez, K
    Lin, AL
    PHYSICAL REVIEW E, 2004, 70 (05):