Dynamics of oxidation Belousov-Zhabotinsky waves in an electric field?

被引:42
|
作者
Sevcikova, H [1 ]
Schreiber, I [1 ]
Marek, M [1 ]
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT CHEM ENGN,CR-16628 PRAGUE 6,CZECH REPUBLIC
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期
关键词
D O I
10.1021/jp961789w
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experiments with oxidation circular waves in a quasi-two-dimensional Belousov-Zhabotinsky reaction medium subject to an external de electric field reveal a variety of wave dynamics scenarios involving wave splitting, reversal, annihilation, and complex pattern formation. We also investigate effects of initial concentration of reactants on the wave dynamics and find marked sensitivity related to excitability of the reaction medium. Two different variants of the Oregonator model are shown to have a common dimensionless representation providing conversion relations between corresponding rate coefficients. Modeling of the waves in an electric field is in qualitative agreement with experiments and predicts a rich structure of complex wave dynamics.
引用
收藏
页码:19153 / 19164
页数:12
相关论文
共 50 条
  • [21] Contextualization of the Belousov-Zhabotinsky reaction
    Diaz, Drew
    Crawford, Mary
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 247
  • [22] Asymmetric spatiotemporal patterns of reduction waves in the Belousov-Zhabotinsky reaction
    Sakamoto, F
    Miyakawa, K
    JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 2001, 70 (08) : 2263 - 2266
  • [23] Experimental survey of spiral dynamics in the Belousov-Zhabotinsky reaction
    Belmonte, AL
    Qi, OY
    Flesselles, JM
    JOURNAL DE PHYSIQUE II, 1997, 7 (10): : 1425 - 1468
  • [24] RECIPES FOR BELOUSOV-ZHABOTINSKY REAGENTS
    JAHNKE, W
    WINFREE, AT
    JOURNAL OF CHEMICAL EDUCATION, 1991, 68 (04) : 320 - 324
  • [25] Model of the Belousov-Zhabotinsky Reaction
    Stys, Dalibor
    Nahlik, Tomas
    Zhyrova, Anna
    Rychtarikova, Renata
    Papacek, Stepan
    Cisar, Petr
    HIGH PERFORMANCE COMPUTING IN SCIENCE AND ENGINEERING, HPCSE 2015, 2016, 9611 : 171 - 185
  • [26] THE PREHISTORY OF THE BELOUSOV-ZHABOTINSKY OSCILLATOR
    WINFREE, AT
    JOURNAL OF CHEMICAL EDUCATION, 1984, 61 (08) : 661 - 663
  • [27] RING-SHAPED WAVES OF INHIBITION IN THE BELOUSOV-ZHABOTINSKY REACTION
    MAREK, M
    KASTANEK, P
    MULLER, SC
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (31): : 7452 - 7454
  • [28] Forced parallel drift of spiral waves in the Belousov-Zhabotinsky reaction
    Schmidt, B
    Muller, SC
    PHYSICAL REVIEW E, 1997, 55 (04): : 4390 - 4393
  • [29] The power law relation of spiral waves in the Belousov-Zhabotinsky reaction
    Li, Y
    Bai, SF
    Qi, OY
    JOURNAL OF CHEMICAL PHYSICS, 2000, 113 (24): : 11280 - 11283
  • [30] SPIRAL WAVES IN A MODEL OF THE FERROIN CATALYZED BELOUSOV-ZHABOTINSKY REACTION
    ROVINSKY, AB
    JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (02): : 217 - 219