Dynamics of oxidation Belousov-Zhabotinsky waves in an electric field?

被引:42
|
作者
Sevcikova, H [1 ]
Schreiber, I [1 ]
Marek, M [1 ]
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT CHEM ENGN,CR-16628 PRAGUE 6,CZECH REPUBLIC
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期
关键词
D O I
10.1021/jp961789w
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experiments with oxidation circular waves in a quasi-two-dimensional Belousov-Zhabotinsky reaction medium subject to an external de electric field reveal a variety of wave dynamics scenarios involving wave splitting, reversal, annihilation, and complex pattern formation. We also investigate effects of initial concentration of reactants on the wave dynamics and find marked sensitivity related to excitability of the reaction medium. Two different variants of the Oregonator model are shown to have a common dimensionless representation providing conversion relations between corresponding rate coefficients. Modeling of the waves in an electric field is in qualitative agreement with experiments and predicts a rich structure of complex wave dynamics.
引用
收藏
页码:19153 / 19164
页数:12
相关论文
共 50 条
  • [11] Dynamics of spiral waves under phase feedback control in a Belousov-Zhabotinsky reaction
    Tung, CK
    Chan, CK
    PHYSICAL REVIEW LETTERS, 2002, 89 (24) : 248302 - 248302
  • [12] Excitation of Waves in a Belousov-Zhabotinsky System in Emulsion Media
    Basavaraja, C.
    Pierson, R.
    Huh, Do Sung
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2008, 29 (11) : 2241 - 2246
  • [13] SPIRAL WAVES IN THE HOMOGENEOUS AND INHOMOGENEOUS BELOUSOV-ZHABOTINSKY REACTION
    ALIEV, RR
    ROVINSKY, AB
    JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (02): : 732 - 736
  • [14] A QUANTITATIVE STUDY OF CHEMICAL WAVES IN THE BELOUSOV-ZHABOTINSKY REACTION
    WOOD, PM
    ROSS, J
    JOURNAL OF CHEMICAL PHYSICS, 1985, 82 (04): : 1924 - 1936
  • [15] Chemical waves with line defects in the Belousov-Zhabotinsky reaction
    Guo, HY
    Li, L
    Wang, HL
    Ouyang, Q
    PHYSICAL REVIEW E, 2004, 69 (05): : 5
  • [16] Mechanism of Spiral Wave Unpinning in the Belousov-Zhabotinsky Reaction with a DC Electric Field
    V. Amrutha, S.
    Sebastian, Anupama
    Sibeesh, Puthiyapurayil
    Punacha, Shreyas
    Shajahan, T. K.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2022, 126 (46): : 19618 - 19626
  • [17] Dynamics of the spiral tip in a closed Belousov-Zhabotinsky reaction
    Zhang, HJ
    Wang, PY
    Zhou, YY
    CHINESE PHYSICS LETTERS, 2005, 22 (06) : 1333 - 1335
  • [18] Pattern dynamics in the Belousov-Zhabotinsky coupled map lattice
    Yoshimoto, M.
    Kurosawa, S.
    INDIAN JOURNAL OF PHYSICS, 2022, 96 (05) : 1489 - 1500
  • [19] Pattern dynamics in the Belousov-Zhabotinsky coupled map lattice
    Minoru Yoshimoto
    Shigeru Kurosawa
    Indian Journal of Physics, 2022, 96 : 1489 - 1500
  • [20] DIFFUSIVE INSTABILITIES AND NONLINEAR DYNAMICS OF THE BELOUSOV-ZHABOTINSKY SYSTEM
    ROVINSKY, AB
    REACTION KINETICS AND CATALYSIS LETTERS, 1990, 42 (02): : 361 - 366