Dynamics of oxidation Belousov-Zhabotinsky waves in an electric field?

被引:42
|
作者
Sevcikova, H [1 ]
Schreiber, I [1 ]
Marek, M [1 ]
机构
[1] PRAGUE INST CHEM TECHNOL,DEPT CHEM ENGN,CR-16628 PRAGUE 6,CZECH REPUBLIC
来源
JOURNAL OF PHYSICAL CHEMISTRY | 1996年 / 100卷 / 49期
关键词
D O I
10.1021/jp961789w
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Experiments with oxidation circular waves in a quasi-two-dimensional Belousov-Zhabotinsky reaction medium subject to an external de electric field reveal a variety of wave dynamics scenarios involving wave splitting, reversal, annihilation, and complex pattern formation. We also investigate effects of initial concentration of reactants on the wave dynamics and find marked sensitivity related to excitability of the reaction medium. Two different variants of the Oregonator model are shown to have a common dimensionless representation providing conversion relations between corresponding rate coefficients. Modeling of the waves in an electric field is in qualitative agreement with experiments and predicts a rich structure of complex wave dynamics.
引用
收藏
页码:19153 / 19164
页数:12
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