The chiral Zn(Il)-Na(I) coordination polymer: Synthesis, crystal structure, thermal and optical properties

被引：13
|
作者：
Yuksel, Fatma [1 ,2 ]
Chumakov, Yurii [1 ,3 ]
Luneau, Dominique [1 ]
机构：
[1] Univ Lyon 1, Lab Multimateriaux & Interfaces, UMR 5615, F-69622 Villeurbanne, France
[2] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey
[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 07期
关键词：
coordination polymer; NLO; Zn(II) complex; chiral complex; crystal engineering;
D O I：
10.1016/j.inoche.2008.03.018
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chiral Zn(Il)-Na(I) coordination polymer with formula [NaZn(acac)(2)(AcO)(EtOH)] (1) has been synthesized, and characterized by H-1 NMR and FT-IR spectra, elemental, X-ray, and thermogravimetric analysis (TGA). X-ray crystallographic study revealed that I crystallizes in the non -centrosymmetric space groups P2(1)2(1)2(1) and exhibits a one-dimensional polymer chain. Linear optical properties were investigated by UV/Vis spectrophotometer techniques. Kurtz-Perry powder second-harmonic-generation (SHG) test confirms the non-linear optical (NLO) property of the grown crystal. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：749 / 753
页数：5
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