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The chiral Zn(Il)-Na(I) coordination polymer: Synthesis, crystal structure, thermal and optical properties
被引:13
|作者:
Yuksel, Fatma
[1
,2
]
Chumakov, Yurii
[1
,3
]
Luneau, Dominique
[1
]
机构:
[1] Univ Lyon 1, Lab Multimateriaux & Interfaces, UMR 5615, F-69622 Villeurbanne, France
[2] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey
[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova
关键词:
coordination polymer;
NLO;
Zn(II) complex;
chiral complex;
crystal engineering;
D O I:
10.1016/j.inoche.2008.03.018
中图分类号:
O61 [无机化学];
学科分类号:
070301 ;
081704 ;
摘要:
The chiral Zn(Il)-Na(I) coordination polymer with formula [NaZn(acac)(2)(AcO)(EtOH)] (1) has been synthesized, and characterized by H-1 NMR and FT-IR spectra, elemental, X-ray, and thermogravimetric analysis (TGA). X-ray crystallographic study revealed that I crystallizes in the non -centrosymmetric space groups P2(1)2(1)2(1) and exhibits a one-dimensional polymer chain. Linear optical properties were investigated by UV/Vis spectrophotometer techniques. Kurtz-Perry powder second-harmonic-generation (SHG) test confirms the non-linear optical (NLO) property of the grown crystal. (c) 2008 Elsevier B.V. All rights reserved.
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页码:749 / 753
页数:5
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