The chiral Zn(Il)-Na(I) coordination polymer: Synthesis, crystal structure, thermal and optical properties

被引:13
|
作者
Yuksel, Fatma [1 ,2 ]
Chumakov, Yurii [1 ,3 ]
Luneau, Dominique [1 ]
机构
[1] Univ Lyon 1, Lab Multimateriaux & Interfaces, UMR 5615, F-69622 Villeurbanne, France
[2] Gebze Inst Technol, Dept Chem, TR-41400 Gebze, Turkey
[3] Moldavian Acad Sci, Inst Appl Phys, Kishinev, Moldova
关键词
coordination polymer; NLO; Zn(II) complex; chiral complex; crystal engineering;
D O I
10.1016/j.inoche.2008.03.018
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The chiral Zn(Il)-Na(I) coordination polymer with formula [NaZn(acac)(2)(AcO)(EtOH)] (1) has been synthesized, and characterized by H-1 NMR and FT-IR spectra, elemental, X-ray, and thermogravimetric analysis (TGA). X-ray crystallographic study revealed that I crystallizes in the non -centrosymmetric space groups P2(1)2(1)2(1) and exhibits a one-dimensional polymer chain. Linear optical properties were investigated by UV/Vis spectrophotometer techniques. Kurtz-Perry powder second-harmonic-generation (SHG) test confirms the non-linear optical (NLO) property of the grown crystal. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:749 / 753
页数:5
相关论文
共 50 条
  • [41] Urothermal Synthesis and Crystal Structure of a Zn(II) Coordination Polymer with a 3-D Supramolecular Structure
    Chen Shun-Yu
    Yang E
    Liu Zi-Sheng
    Ye Xiao-Long
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (04) : 535 - 538
  • [42] Synthesis, Crystal Structure, and Properties of a Zn(II) Coordination Polymer Based on a Difunctional Ligand Containing Triazolyl and Carboxyl Groups
    Li, Jia-Le
    Li, Wei-Dong
    He, Zi-Wei
    Han, Shuai-Shuai
    Chen, Shui-Sheng
    CRYSTALS, 2018, 8 (11):
  • [43] Synthesis, Crystal Structure and Optical Properties of Zinc Coordination Polymer from 5-Aminonicotinic Acid Ligand
    Zhang Chun-Li
    Qin Ling
    Zheng He-Gen
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2014, 30 (04) : 800 - 804
  • [44] Supramolecular Ag(I) coordination polymer directed by argentophilic interactions: Synthesis, crystal structure, luminescent and catalytic properties
    Wang, Junmin
    Liu, Huimin
    JOURNAL OF MOLECULAR STRUCTURE, 2018, 1173 : 833 - 836
  • [45] Synthesis, Crystal Structure and Properties of a Copper(Ⅰ) Coordination Polymer Based on Benzimidazole Derivative
    贾强强
    李俊毅
    张浩玺
    陈立庄
    王国喜
    Chinese Journal of Structural Chemistry, 2020, 39 (11) : 2021 - 2026
  • [46] Synthesis, crystal structure and adsorption properties of a novel Mn(II) coordination polymer
    Cui, Lian-Sheng
    Gan, Yong-Le
    Li, Yuan-Cheng
    Meng, Jun-Rong
    JOURNAL OF MOLECULAR STRUCTURE, 2017, 1147 : 317 - 321
  • [47] Hydrothermal Synthesis and Crystal Structure of a New 3D Zn(II) Coordination Polymer
    Li, Xianjiang
    Shen, Bo
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 (14) : 8235 - 8236
  • [48] Crystal Structure and Luminescent Properties of a Zn(II) Coordination Polymer Assembled by Mixed-ligand
    Qin Xiao-Huan
    Zou Hua-Hong
    Gui Liu-Cheng
    Liao Yong-Zhi
    Li Hai-Ye
    Huang Fu-Ping
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2014, 33 (09) : 1293 - 1299
  • [49] Synthesis, crystal structure and properties of the novel chiral 3D coordination polymer with S-carboxymethyl-L-cysteine
    Xu, Wei
    Liu, Wen
    Yao, Fang-Yang
    Zheng, Yue-Qing
    INORGANICA CHIMICA ACTA, 2011, 365 (01) : 297 - 301
  • [50] Mononuclear and coordination polymer of silver(I) complexes: design, synthesis, and crystal structure analysis
    Rahazat, Nur R. A.
    Haque, Rosenani A.
    Ng, Seik W.
    Razali, Mohd. R.
    JOURNAL OF COORDINATION CHEMISTRY, 2015, 68 (08) : 1317 - 1331