Synthesis, crystal structure, and properties of a new zinc coordination polymer [Zn(PMP)2Cl]n

被引：7

作者：

Xu, Rui-Bo ^{[2
,3
]}

Xu, Xing-You ^{[1
]}

Yin, Yu-He ^{[4
]}

Wang, Ming-Yan ^{[2
]}

Yang, Xu-Jie ^{[3
]}

Xu, Qian-Qian ^{[2
]}

Ma, Li-Ping ^{[2
]}

机构：

[1] Huaiyin Inst Technol, Huaian 223003, Peoples R China

[2] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Peoples R China

[3] Nanjing Univ Sci & Technol, Lab Soft Chem & Funct Mat, Minist Educ, Nanjing 210094, Peoples R China

[4] Changchun Univ Technol, Sch Chem & Life Sci, Changchun 130012, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 24期

关键词：

PMP; Zinc coordination polymer; Crystal structure; Electrochemistry; Thermal analysis; HYDROTHERMAL SYNTHESIS; ZN(II) COMPLEXES; LUMINESCENCE; FLUORESCENCE; LIGAND;

D O I：

10.1080/00958970903207344

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new coordination polymer [Zn(PMP)(2)Cl](n) (PMP = 1-phenyl-3-methyl-5-pyrazolone) has been prepared by the reaction of zinc chloride and PMP, and characterized by elemental analysis, IR, UV, and fluorescence spectra, TG/DTA, and electrochemical analysis. Single crystal X-ray diffraction revealed that the complex is monoclinic, space group P 2(1)/n, with a = 10.850(17), b = 17.578(2), c = 10.997(18) angstrom, beta = 104.999(3)degrees, V = 2025.8(5)angstrom(3), Z = 4, D-c = 1.470 mg m(-3), F(000) = 920, goodness-of-fit = 0.905, and R-1 = 0.0441. The complex is a 1-D coordination polymer, and the coordination geometry of Zn(II) is a distorted tetrahedron.

引用

页码：3905 / 3912

页数：8

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