A New Zn(II) Coordination Polymer With Helical Character: Synthesis and Crystal Structure

被引：0
|
作者：
Li, Hongliang [1 ]
机构：
[1] Dezhou Univ, Coll Chem & Chem Engn, Dezhou 253023, Shandong, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2015年 / 45卷 / 08期
关键词：
Zn(II); coordination polymer; crystal structure; luminescence; HYDROTHERMAL SYNTHESIS; LIGAND SYNTHESIS; PROPERTY; TOPOLOGY; ACID;
D O I：
10.1080/15533174.2013.862674
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new Zn(II) coordination polymer with and has been prepared by hydrothermal synthesis and characterized by single-crystal X-ray diffraction, IR, and element analysis. Complex [Zn(bda)(bpa)](n) (1) [H(2)bda = 2,4-biphenyl-dicarboxylic acid, and bpa = bis(4-pyridyl)amine is monoclinic, space group P2(1)/c with a = 16.518(5), b = 8.600 (5), c = 16.819 (5) angstrom, = 115.318 (5)degrees, V = 2159.7 (16) angstrom(3), Z = 4, M-r = 476.78, D-c = 1.466g/cm(3), F(000) = 976, and = 1.173mm(-1). The final refinement gave R = 0.0355 and wR = 0.0670 for 2534 reflections with I > 2 sigma(I). X-ray diffraction analysis reveals that the complex 1 displays a two-dimensional structure with helical chain substructure.
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页码：1135 / 1137
页数：3
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