The synthesis and structures of acyclic and macrocyclic thio-, seleno- and telluro-ether complexes of the metallic and metalloid elements of Groups 13-16 reported since 2000 are described. The diverse structures range from discrete monomers through to infinite 1-, 2- or 3-D polymers. The coordination chemistry in this area is quite different to familiar d-block chemistry and the underlying factors are explored.
机构:
Institut für Anorganische Chemie, TU Bergakademie Freiberg, Leipziger Str. 29, Freiberg,09599, GermanyInstitut für Anorganische Chemie, TU Bergakademie Freiberg, Leipziger Str. 29, Freiberg,09599, Germany
Böhme, Uwe
Riedel, Sophie
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机构:
Institut für Anorganische Chemie, TU Bergakademie Freiberg, Leipziger Str. 29, Freiberg,09599, GermanyInstitut für Anorganische Chemie, TU Bergakademie Freiberg, Leipziger Str. 29, Freiberg,09599, Germany