The chemistry of the p-block elements with thioether, selenoether and telluroether ligands

被引:42
|
作者
Levason, William [1 ]
Reid, Gillian [1 ]
Zhang, Wenjian [1 ]
机构
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
基金
英国工程与自然科学研究理事会;
关键词
SEMICONDUCTIVE COORDINATION NETWORKS; CHEMICAL-VAPOR-DEPOSITION; STRUCTURAL-PROPERTIES; HALIDE-COMPLEXES; ETHER COMPLEXES; METAL-COMPLEXES; THIN-FILMS; CVD; TETRACHLORIDE; TETRAHALIDES;
D O I
10.1039/c1dt10317b
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis and structures of acyclic and macrocyclic thio-, seleno- and telluro-ether complexes of the metallic and metalloid elements of Groups 13-16 reported since 2000 are described. The diverse structures range from discrete monomers through to infinite 1-, 2- or 3-D polymers. The coordination chemistry in this area is quite different to familiar d-block chemistry and the underlying factors are explored.
引用
收藏
页码:8491 / 8506
页数:16
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