A two-dimensional layer in N,N′-bis-[2-(hydroxymethyl)benzyl]ethylenediamine and a three-dimensional network in N,N′-bis[2-(hydroxymethyl)benzyl]ethylenediammonium bis(perchlorate)

被引：0
|
作者：
Zhang, Min [1 ]
Meng, Xiang-Gao [1 ]
Hu, Zong-Qiu [1 ]
Xu, Xing-Man [1 ]
机构：
[1] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2008年 / 64卷 / o272-o275期
关键词：
D O I：
10.1107/S0108270108008937
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In both title compounds, C18H24N2O2, (Ia), and C18H26N2O22+center dot 2ClO(4)(-), (II), respectively, the two aryl rings are strictly parallel, with an inversion centre lying at the mid-point of each central CH2-CH2 bond. Molecules in (Ia) are linked into two-dimensional layers by N-H center dot center dot center dot O hydrogen bonds. The component ions in (II) are joined together by a combination of N/O/C-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi and anion center dot center dot center dot pi interactions, forming a three-dimensional network. A structural understanding of (Ia) and (II) may provide some useful information about how and why their metal-organic complexes display various biological activities and function in catalytic processes.
引用
收藏
页码：O272 / O275
页数：4
相关论文
共 50 条
  • [41] {Tris[2-(2-pyridylmethyleneamino-κ2N,N′)-ethyl]amine}cadmium(II) bis(perchlorate)
    He, Hong-Shan
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : M346 - M347
  • [42] N,N′-Bis(2,3-dichlorobenzylidene)ethylenediamine
    Khaniani, Yeganeh
    Badiei, Alireza
    Ziarani, Ghodsi Mohammadi
    Abbasi, Alireza
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4616 - U4207
  • [43] N,N′-bis(2,4-dichlorobenzylidene)ethylenediamine
    Abbasi, Alireza
    Ziarani, Ghodsi Mohammadi
    Badiei, Alireza
    Khaniani, Yeganeh
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4736 - U5307
  • [44] SYNTHESIS OF N,N'-BIS(2-FORMYLPHENYL)ETHYLENEDIAMINE
    FORMANOVSKII, AA
    ZHURNAL ORGANICHESKOI KHIMII, 1986, 22 (05): : 1103 - 1105
  • [45] Bis[N,N-′bis(2-fluorobenzylidene)ethylenediamine-κ2N,N′]silver(I) nitrate
    Usman, A
    Fun, HK
    Zhu, HL
    Liu, QX
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : M140 - M141
  • [46] Bis{2-[(2,4-dimethylphenyl)iminomethyl]pyridine-κ2N,N′}bis(thiocyanato-κN)cadmium
    Malekshahian, Mohammad
    Olyai, Mohamad Reza Talei Bavil
    Notash, Behrouz
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2012, 68 : M218 - U1263
  • [47] Bis-μ-hydroxo-bis[(benzyl)(nitrosyl-N)(η5- pentamethylcyclopentadienyl)-molybdenum]
    Legzdins, Peter
    Lundmark, Penelope J.
    Rettig, Steven J.
    Acta Crystallographica, Section C: Crystal Structure Communications, 1996, 52 (Pt 5): : 1113 - 1115
  • [48] trans-Bis(ethylenediamine)bis{2-[N-(2-hydroxyethyl)oxamoylamino]benzoato}nickel(II)
    Yu, Jun
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1140 - U906
  • [49] [μ-N,N prime -Bis(2-pyridylethyl)oxamide]bis-[acetatocopper(II)]
    Francisco, Regina H. P.
    Gambardella, M. Teresa Do P.
    Rodrigues, Ana M. G. D.
    De, Paula, M.
    De, Sousa, Gerimario F.
    Acta Crystallographica, Section C: Crystal Structure Communications, 1999, 55 (11): : 1791 - 1793
  • [50] Crystal structure of an eight-coordinate terbium(III) ion chelated by N,N '-bis(2-hydroxybenzyl)-N,N '-bis(pyridin-2-ylmethyl)ethylenediamine (bbpen(2-)) and nitrate
    Gregorio, Thaiane
    Ruediger, Andre Luis
    Nunes, Giovana G.
    Soares, Jaisa F.
    Hughes, David L.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 65 - +
12345