A two-dimensional layer in N,N′-bis-[2-(hydroxymethyl)benzyl]ethylenediamine and a three-dimensional network in N,N′-bis[2-(hydroxymethyl)benzyl]ethylenediammonium bis(perchlorate)

被引：0

作者：

Zhang, Min ^{[1
]}

Meng, Xiang-Gao ^{[1
]}

Hu, Zong-Qiu ^{[1
]}

Xu, Xing-Man ^{[1
]}

机构：

[1] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2008年 / 64卷 / o272-o275期

关键词：

D O I：

10.1107/S0108270108008937

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In both title compounds, C18H24N2O2, (Ia), and C18H26N2O22+center dot 2ClO(4)(-), (II), respectively, the two aryl rings are strictly parallel, with an inversion centre lying at the mid-point of each central CH2-CH2 bond. Molecules in (Ia) are linked into two-dimensional layers by N-H center dot center dot center dot O hydrogen bonds. The component ions in (II) are joined together by a combination of N/O/C-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi and anion center dot center dot center dot pi interactions, forming a three-dimensional network. A structural understanding of (Ia) and (II) may provide some useful information about how and why their metal-organic complexes display various biological activities and function in catalytic processes.

引用

页码：O272 / O275

页数：4

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