A two-dimensional layer in N,N′-bis-[2-(hydroxymethyl)benzyl]ethylenediamine and a three-dimensional network in N,N′-bis[2-(hydroxymethyl)benzyl]ethylenediammonium bis(perchlorate)

被引：0
|
作者：
Zhang, Min [1 ]
Meng, Xiang-Gao [1 ]
Hu, Zong-Qiu [1 ]
Xu, Xing-Man [1 ]
机构：
[1] Cent China Normal Univ, Dept Chem, Wuhan 430079, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2008年 / 64卷 / o272-o275期
关键词：
D O I：
10.1107/S0108270108008937
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In both title compounds, C18H24N2O2, (Ia), and C18H26N2O22+center dot 2ClO(4)(-), (II), respectively, the two aryl rings are strictly parallel, with an inversion centre lying at the mid-point of each central CH2-CH2 bond. Molecules in (Ia) are linked into two-dimensional layers by N-H center dot center dot center dot O hydrogen bonds. The component ions in (II) are joined together by a combination of N/O/C-H center dot center dot center dot O hydrogen bonds and C-H center dot center dot center dot pi and anion center dot center dot center dot pi interactions, forming a three-dimensional network. A structural understanding of (Ia) and (II) may provide some useful information about how and why their metal-organic complexes display various biological activities and function in catalytic processes.
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页码：O272 / O275
页数：4
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