Application of novel phosphine oxazoline ligands in asymmetric allylations of 4-acyloxy-2-pentene derivatives

被引：26

作者：

Burgess, K ^{[1
]}

Porte, AM ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 14期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0957-4166(98)00230-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A library of novel phosphine oxazoline ligands 2 was tested in the asymmetric allylation of 4-acyloxy-2-pentenes 1. High throughput screening techniques were employed to accelerate this process. The data accumulated allowed the extent of asymmetric induction to be correlated with the ligand substituent R and ligand-to-metal ratios. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2465 / 2469

页数：5

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