Application of novel phosphine oxazoline ligands in asymmetric allylations of 4-acyloxy-2-pentene derivatives

被引：26
|
作者：
Burgess, K [1 ]
Porte, AM [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
来源：
TETRAHEDRON-ASYMMETRY | 1998年 / 9卷 / 14期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0957-4166(98)00230-4
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A library of novel phosphine oxazoline ligands 2 was tested in the asymmetric allylation of 4-acyloxy-2-pentenes 1. High throughput screening techniques were employed to accelerate this process. The data accumulated allowed the extent of asymmetric induction to be correlated with the ligand substituent R and ligand-to-metal ratios. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2465 / 2469
页数：5
相关论文
共 50 条
  • [21] Syntheses of novel C2-symmetric chiral bis(oxazoline) ligands and their application in titanium catalyzed diethylzinc additions to aldehydes
    Zhang, CH
    Liu, YJ
    Yang, NF
    Yang, LW
    Yang, G
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2004, 24 (08) : 977 - 980
  • [22] PINDY and MINDY:: Novel 2,2′-bipyridine-type ligands and their application in asymmetric catalysis.
    Kocovsky, P
    Malkov, AV
    Bella, M
    Bell, M
    Pernazza, D
    Stara, IG
    Stary, I
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2001, 221 : U141 - U141
  • [23] PHOSPHINEGOLD(I) DERIVATIVES OF THE METAL-RICH METALLABORANE, HFE4(CO)12BH2 - A NOVEL PHOSPHINE EXCHANGE INVOLVING CATION AND CLUSTER-BOUND PHOSPHINE-LIGANDS
    HARPP, KS
    HOUSECROFT, CE
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 340 (03) : 389 - 396
  • [24] The design, synthesis and application of imidazolium-tagged ferrocenyl oxazoline phosphine ligands for the asymmetric 1,3-dipolar cycloaddition of azomethine ylides with nitroalkenes: ion effect for enhancing the reactivity, stereoselectivity and recyclability
    Dai, Li
    Xu, Di
    Dong, Xiao
    Zhou, Zhiming
    TETRAHEDRON-ASYMMETRY, 2015, 26 (07) : 350 - 360
  • [25] Novel highly modular C2-symmetric oxazoline ligands-application in titanium-catalyzed diethylzinc additions to aldehydes
    Pastor, IM
    Adolfsson, H
    TETRAHEDRON LETTERS, 2002, 43 (09) : 1743 - 1746
  • [26] Development of a new class of (1S,3R 4R)-2-azabicyclo[2.2.1]heptane-oxazoline ligands and their application in asymmetric transfer hydrogenation
    Trifonova, A
    Källström, KE
    Andersson, PG
    TETRAHEDRON, 2004, 60 (15) : 3393 - 3403
  • [27] Synthesis of a Novel C2-Symmetric Bis-oxazoline (=Bis[4,5-dihydrooxazole]) and Its Application as Chiral Ligand in Asymmetric Transition Metal Catalysis
    Gok, Yasar
    Van der Eycken, Johan
    HELVETICA CHIMICA ACTA, 2012, 95 (05) : 831 - 838
  • [28] Chiral Naphthyl-C2-Indole as Scaffold for Phosphine Organocatalysis: Application in Asymmetric Formal [4+2] Cycloaddition Reactions
    He, Tingting
    Peng, Lei
    Li, Shan
    Hu, Fangli
    Xie, Chuandong
    Huang, Shengli
    Jia, Shiqi
    Qin, Wenling
    Yan, Hailong
    ORGANIC LETTERS, 2020, 22 (17) : 6966 - 6971
  • [29] Novel chiral 1,2-diphenyl-2-aminophosphine phosphinite ligands and their application in asymmetric catalytic hydrogenation
    Mi, AQ
    Lou, RL
    Jiang, YZ
    Hu, WH
    Fu, FM
    Li, Z
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U469 - U469
  • [30] Synthesis of novel derivatives of (1S,4S)-2,5-diazabicyclo[2.2.1]heptane and their evaluation as potential ligands in asymmetric catalysis
    Melgar-Fernandez, Roberto
    Gonzalez-Olvera, Rodrigo
    Olivares-Romero, J. Luis
    Gonzalez-Lopez, Vianney
    Romero-Ponce, Leticia
    Ramirez-Zarate, Maria del Refugio
    Demare, Patricia
    Regla, Ignacio
    Juaristi, Eusebio
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2008, 2008 (04) : 655 - 672
12345