Encapsulation versus Aggregation of Metal-Organic Cages Controlled by Guest Size Variation

被引：50
|
作者：
Clever, Guido H. [1 ]
Kawamura, Wataru [1 ]
Shionoya, Mitsuhiko [1 ]
机构：
[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 11期
关键词：
PALLADIUM(II);
D O I：
10.1021/ic200517r
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The strength and mode of binding (inside vs outside) of bisanionic guest molecules to a cationic, self-assembled metal-organic cage depend on their size and the stoichiometry of the addition.(1) Herein we show that the composition of the solid/liquid phase of a heterogeneous system can be kinetically controlled by the order of the addition of two different guest compounds.
引用
收藏
页码：4689 / 4691
页数：3
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