Encapsulation versus Aggregation of Metal-Organic Cages Controlled by Guest Size Variation

被引：50

作者：

Clever, Guido H. ^{[1
]}

Kawamura, Wataru ^{[1
]}

Shionoya, Mitsuhiko ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

来源：

INORGANIC CHEMISTRY | 2011年 / 50卷 / 11期

关键词：

PALLADIUM(II);

D O I：

10.1021/ic200517r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The strength and mode of binding (inside vs outside) of bisanionic guest molecules to a cationic, self-assembled metal-organic cage depend on their size and the stoichiometry of the addition.(1) Herein we show that the composition of the solid/liquid phase of a heterogeneous system can be kinetically controlled by the order of the addition of two different guest compounds.

引用

页码：4689 / 4691

页数：3

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