Pulsed electrodeposition of zinc-manganese alloys

被引：12
|
作者：
Danilov, FI [1 ]
Gerasimov, VV [1 ]
Sukhomlin, DA [1 ]
机构：
[1] Ukraine State Univ Chem Technol, UA-320640 Dnepropetrovsk, Ukraine
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2001年 / 37卷 / 03期
关键词：
Sulfate; Zinc; Physical Chemistry; Hydroxide; Manganese;
D O I：
10.1023/A:1009037616542
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
High-quality Zn-Mn coatings with an Mn content reaching 50% are obtained from citrate-sulfate solutions in pulsed electrolysis at a pulse length of 0.1 ms to 1 s. Due to the formation of a blocking film of citrate-hydroxide zinc compounds, cathodic potential increases with time, which helps reach a codeposition potential of Mn ions. An electrolysis with a pulsed current superposed on a de increases the Mn content and makes no impact on the coating quality.
引用
收藏
页码：308 / 310
页数：3
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