Pulsed electrodeposition of zinc-manganese alloys

被引：12
|
作者：
Danilov, FI [1 ]
Gerasimov, VV [1 ]
Sukhomlin, DA [1 ]
机构：
[1] Ukraine State Univ Chem Technol, UA-320640 Dnepropetrovsk, Ukraine
来源：
RUSSIAN JOURNAL OF ELECTROCHEMISTRY | 2001年 / 37卷 / 03期
关键词：
Sulfate; Zinc; Physical Chemistry; Hydroxide; Manganese;
D O I：
10.1023/A:1009037616542
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
High-quality Zn-Mn coatings with an Mn content reaching 50% are obtained from citrate-sulfate solutions in pulsed electrolysis at a pulse length of 0.1 ms to 1 s. Due to the formation of a blocking film of citrate-hydroxide zinc compounds, cathodic potential increases with time, which helps reach a codeposition potential of Mn ions. An electrolysis with a pulsed current superposed on a de increases the Mn content and makes no impact on the coating quality.
引用
收藏
页码：308 / 310
页数：3
相关论文
共 50 条
  • [41] PVDF-HFP binder for advanced zinc-manganese batteries
    Ma, Shu-ci
    Shi, Xiao-dong
    Liu, Zhe-xuan
    Zhou, Yi-fan
    Wang, Pin-ji
    Zhou, Jiang
    Liang, Shu-quan
    [J]. TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA, 2022, 32 (09) : 3005 - 3014
  • [42] Zinc-manganese plating and related post treatments - Practical experiences
    Verberne, W.M.J.C.
    [J]. Galvanotechnik, 2002, 93 (06): : 1485 - 1488
  • [43] Action of Bismuth Ions on Electronic Structure of Zinc-Manganese Ferrites
    Kopaev, A. V.
    [J]. METALLOFIZIKA I NOVEISHIE TEKHNOLOGII, 2009, 31 (08): : 1035 - 1040
  • [44] The study of composite substituting mercury corrosion inhibitors for zinc in zinc-manganese battery
    Cui, Yun
    Zhao, Dishun
    Qu, Hai
    Qu, Guanwei
    Liu, Jing
    Ren, Peibing
    [J]. CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING III, PTS 1-3, 2014, 881-883 : 102 - +
  • [45] ELECTRODEPOSITION OF ZINC-ALLOYS
    BOOSE, C
    [J]. PLATING AND SURFACE FINISHING, 1987, 74 (02): : 43 - 43
  • [46] Electrodeposition of gradient zinc alloys
    Lee, EC
    Ahn, JG
    Ma, CI
    [J]. PLATING AND SURFACE FINISHING, 2001, 88 (05): : 124 - 126
  • [47] Research on mercury-free alkaline zinc-manganese battery
    Wei, Jie
    Zhou, Ding
    Zhou, Derui
    [J]. Dianyuan Jishu/Chinese Journal of Power Sources, 2000, 24 (01): : 8 - 11
  • [48] MN-MN EXCHANGE CONSTANTS IN ZINC-MANGANESE CHALCOGENIDES
    GIEBULTOWICZ, TM
    RHYNE, JJ
    FURDYNA, JK
    [J]. JOURNAL OF APPLIED PHYSICS, 1987, 61 (08) : 3537 - 3539
  • [49] Effect of some amidopoly ethylamine on corrosion of zinc electrode used in zinc-manganese batteries
    Abdallah, M.
    El-Etre, A. Y.
    Moustafa, M. F.
    [J]. PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2011, 47 (02) : 246 - 252
  • [50] Effect of some amidopoly ethylamine on corrosion of zinc electrode used in zinc-manganese batteries
    M. Abdallah
    A. Y. El-Etre
    M. F. Moustafa
    [J]. Protection of Metals and Physical Chemistry of Surfaces, 2011, 47 : 246 - 252
12345