Nanoporous gold as non-enzymatic sensor for hydrogen peroxide

被引:208
|
作者
Meng, Fanhui [2 ]
Yan, Xiuling [2 ,3 ]
Liu, Jianguo [1 ]
Gu, Jun [1 ]
Zou, Zhigang [1 ]
机构
[1] Nanjing Univ, Ecomat & Renewable Energy Res Ctr, Dept Mat Sci & Engn, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Shandong Univ, Sch Chem & Chem Engn, Jinan 250100, Peoples R China
[3] Ili Normal Univ, Sch Chem & Biosci, Xinjiang 835000, Peoples R China
基金
美国国家科学基金会;
关键词
Nanoporous gold; Electrocatalysis; H(2)O(2) detection; H(2)O(2) sensor; Dealloying; ELECTROCATALYTIC REDUCTION; ELECTROCHEMICAL DETECTION; ELECTRODE; H2O2; OXIDATION; SURFACE; NANOPARTICLES; FABRICATION; MECHANISM; GLUCOSE;
D O I
10.1016/j.electacta.2011.02.105
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Nanoporous gold (NPG) fabricated by dealloying Au-Ag film was investigated for the non-enzymatic detection of H(2)O(2). The apparent activation energy of H(2)O(2) electrochemical reduction on NPG was found to be as low as similar to 30 kJ mol(-1). The reduction currents at -0.4V vs. SCE demonstrated a strict linear dependence in a wide H(2)O(2) concentration region from 10 mu M to 8 mM with a detection limit 3.26 mu M. Furthermore, the biosensor based on NPG exhibited high selectivity, good reproducibility, and long-term stability. These results indicate that NPG could be a promising electrochemical material for H(2)O(2) detection. (C) 2011 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4657 / 4662
页数:6
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