cis-bis[2-(diphenylphosphino)benzene-thiolato-κ2P,S]palladium(II)

被引：4
|
作者：
Fierro-Arias, Jaime [1 ]
Morales-Morales, David [1 ]
Hernandez-Ortega, Simon [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808026718
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Pd(C18H14PS)(2)], was synthesized by the reaction of (Ph2PC6H4SH) with [PdCl2(NCC6H5)(2)] in a 2: 1 molar ratio in the presence of a slight excess of NEt3 as base in dichloromethane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C18H14PS)(2)]center dot CH2Cl2.
引用
收藏
页码：M1196 / U858
页数：9
相关论文
共 50 条
  • [1] Bis[cis-bis(diphenylphosphino)ethene-κ2P,P′]copper(I) tetrafluoridoborate ethanol solvate
    Healy, Peter C.
    Loughrey, Bradley T.
    Williams, Michael L.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M500 - U397
  • [2] [2-(Diphenylphosphanyl)benzenethiolato-κ2P,S](pyridine-2-thiolato-κS)(triphenylphosphine-κP)palladium(II)
    Rios-Sanchez, Raul
    Hernandez-Ortega, Simon
    Morales-Morales, David
    Avila-Sorrosa, Alcives
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M1170 - U1191
  • [3] Dichlorido{[(diphenylphosphino)methyl]bis(2-methylphenyl)phosphine-κ2P,P′}palladium(II)
    Badgett, Ansonia H.
    Gray, Danielle L.
    Shelby, Quinetta D.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M1233 - +
  • [4] cis-[bis(diphenylphosphino)ethane-κ2P,P′]dichlororuthenium(II) dichloromethane disolvate
    Russo, L
    Figueira, J
    Rodrigues, J
    Rissanen, K
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : M1154 - M1155
  • [5] [Bis(diphenylphosphino)methane-κ2P,P′]dichloridopalladium(II)
    Shahid, Muhammad
    Imtiaz-ud-Din
    Mazhar, Muhammad
    Zeller, Matthias
    Hunter, Allen D.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M158 - U438
  • [6] cis-{trans-1,2-Bis[2-(diphenylphosphino)benzamido]cyclohexane-κ2P,P′} dichloroplatinum(II) chloroform trisolvate
    Burger, S
    Therrien, B
    Süss-Fink, G
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2004, 60 : M1163 - M1165
  • [7] cis-Bis(thiosemicarbazide-k2N1,S)palladium(II) dinitrate
    Dorazco-Gonzalez, Alejandro
    Hernandez-Ortega, Simon
    Valdes-Martinez, Jesus
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1120 - M1121
  • [8] CRYSTAL-STRUCTURE OF CIS-BIS(DIPHENYLPHOSPHINO)ETHENE, ((C6H5)2P)2C2H2
    JONES, PG
    GIMENO, MC
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1994, 209 (08): : 688 - 689
  • [9] [Bis(diphenylphosphino)amine-κ2P,P′][1,3-bis(diphenylphosphino)propane-κ2P,P′]platinum(II) dichloride dichloromethane solvate
    Irisli, S
    Sen, A
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2097 - M2099
  • [10] SYNTHESIS OF CIS-BIS(PHOSPHINE)BIS(THIOLATO)PLATINUM(II) AND TRANS-BIS(PHOSPHINE)BIS(THIOLATO)PLATINUM(II) COMPLEXES, (PR3)2PT(SR')2
    LAI, RD
    SHAVER, A
    INORGANIC CHEMISTRY, 1981, 20 (02) : 477 - 480
12345