[Bis(diphenylphosphino)amine-κ2P,P′][1,3-bis(diphenylphosphino)propane-κ2P,P′]platinum(II) dichloride dichloromethane solvate

被引:2
|
作者
Irisli, S [1 ]
Sen, A [1 ]
机构
[1] Univ Ege, Fac Sci, Dept Chem, TR-35100 Izmir, Turkey
关键词
D O I
10.1107/S1600536805029880
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [ Pt( C24H21NP2)( C27H26P2)] Cl-2 center dot CH2Cl2 or [ Pt( dppa)( dppp)] Cl-2 center dot CH2Cl2, where dppa is bis( diphenylphosphino) amine and dppp is 1,3-bis( diphenylphosphino) propane, has two different chelate rings. The Pt II atom has a distorted square-planar geometry. The six-membered chelate ring of dppp has a chair conformation. There is a hydrogen bond between the dppa N - H group and a Cl- counter-ion.
引用
收藏
页码:M2097 / M2099
页数:3
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