[1,3-Bis(diphenylphosphino)propane-k2P,P′]diiodido(perfluoropropyl)-rhodium(III) dichloromethane solvate

被引：0
|
作者：
Panthi, Basu [1 ]
Gipson, Stephen L. [1 ]
Franken, Andreas [1 ]
机构：
[1] Baylor Univ, Dept Chem, Waco, TX 76798 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808029978
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The structure of the title compound, [RhI2(C3F7)(C27H26P2)]center dot CH2Cl2, at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh - C bond is relatively short at 1.996 (6) angstrom. This short metal - carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.
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页码：M1330 / U3044
页数：11
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