cis-bis[2-(diphenylphosphino)benzene-thiolato-κ2P,S]palladium(II)

被引：4

作者：

Fierro-Arias, Jaime ^{[1
]}

Morales-Morales, David ^{[1
]}

Hernandez-Ortega, Simon ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷

关键词：

D O I：

10.1107/S1600536808026718

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Pd(C18H14PS)(2)], was synthesized by the reaction of (Ph2PC6H4SH) with [PdCl2(NCC6H5)(2)] in a 2: 1 molar ratio in the presence of a slight excess of NEt3 as base in dichloromethane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C18H14PS)(2)]center dot CH2Cl2.

引用

页码：M1196 / U858

页数：9

共 50 条

[21] BIS(2-(DIMETHYLPHOSPHINO)ETHANE-1-THIOLATO)-NICKEL(II), BIS(2-(DIMETHYLPHOSPHINO)ETHANE-1-THIOLATO)-PALLADIUM(II), AND BIS(2-(DIMETHYLPHOSPHINO)ETHANE-1-THIOLATO)-PLATINUM(II) COMPLEXES, AND MOLECULAR-STRUCTURE OF THE NICKEL(II) COMPLEX
KITA, M
YAMAMOTO, T
KASHIWABARA, K
FUJITA, J
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1992, 65 (08) : 2272 - 2274
[22] Cis-Bis(2,2′-Azopyridinido)dicarbonylruthenium(II)
Takase, Tsugiko
Kainuma, Shuya
Kanno, Takatoshi
Oyama, Dai
MOLBANK, 2021, 2021 (01) : 1 - 5
[23] Bis[μ-bis(diphenylphosphino)methane-κ2P:P′]-bis[(saccharinato-κN)palladium(I)] dichloromethane solvate
Henderson, W
Nicholson, BK
Chung, DC
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2002, 58 : m432 - m433
[24] The influence of metal coordination on ligand geometry:: the structure of 2-(diphenylphosphino)acetophenone and bis(2-(diphenylphosphino)acetophenone)palladium(II)bistriflate
Johansson, MH
Andersson, C
Oskarsson, Å
JOURNAL OF MOLECULAR STRUCTURE, 2002, 606 (1-3) : 51 - 59
[25] The influence of metal coordination on ligand geometry:: The structures of 2-(diphenylphosphino)benzylmethylether and bis(2-(diphenylphosphino)benzylmethylether)palladium(II)triflate
Andersson, C
Friedrich, J
Johansson, MH
Oskarsson, Å
JOURNAL OF MOLECULAR STRUCTURE, 1999, 479 (01) : 1 - 11
[26] [Bis(diphenylphosphino)methane-κ2P,P′][bis(diphenylthiophosphinyl)methane-κ2S,S′]-platinum(II) bis(perchlorate) acetone solvate
Alkan, L
Irisli, S
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2706 - M2708
[27] CRYSTAL-STRUCTURE OF [BIS 1,2-(DIPHENYLPHOSPHINO)ETHANE]-BIS(PYRIDINE-2-THIOLATO)RUTHENIUM(II)
TIEKINK, ERT
LOBANA, TS
SINGH, R
JOURNAL OF CRYSTALLOGRAPHIC AND SPECTROSCOPIC RESEARCH, 1991, 21 (02): : 205 - 208
[28] [N,N-Bis(diphenylphosphino)propylamine-κ2P,P′]dichloridoplatinum(II)
Cloete, Nicoline
Visser, Hendrik G.
Roodt, Andreas
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M51 - U594
[29] SYNTHESIS AND CHARACTERIZATION OF CIS-BIS[(P-TOLYSULFONYL) METHYL]PALLADIUM(II) COMPLEXES
ESPINET, P
MARTINEZILARDUYA, JM
PEREZBRISO, C
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 447 (01) : 145 - 152
[30] [2-(1-Acetoxyethyl)-1,1′-bis(diphenylphosphino)ferrocene-κ2P,P′]dichloridoplatinum(II) dichloromethane solvate
Spencer, Lara C.
Bjelosevic, Haris
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M1536 - U583

← 1 2 3 4 5 →