cis-bis[2-(diphenylphosphino)benzene-thiolato-κ2P,S]palladium(II)

被引：4
|
作者：
Fierro-Arias, Jaime [1 ]
Morales-Morales, David [1 ]
Hernandez-Ortega, Simon [1 ]
机构：
[1] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808026718
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Pd(C18H14PS)(2)], was synthesized by the reaction of (Ph2PC6H4SH) with [PdCl2(NCC6H5)(2)] in a 2: 1 molar ratio in the presence of a slight excess of NEt3 as base in dichloromethane. The compound crystallizes with the Pd(II) atom on a twofold rotation axis. The palladium center has a slightly distorted square-planar environment, with the two P S chelating ligands adopting a cis configuration. The present structure is a pseudo-polymorph of [Pd(C18H14PS)(2)]center dot CH2Cl2.
引用
收藏
页码：M1196 / U858
页数：9
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