Tin and Lead Phosphanido Complexes: Reactivity with Chalcogens

被引：5

作者：

Tam, Eric C. Y. ^{[1
]}

Apperley, David C. ^{[2
]}

Smith, J. David ^{[1
]}

Coles, Martyn P. ^{[1
,3
]}

Fulton, J. Robin ^{[1
,3
]}

机构：

[1] Univ Sussex, Dept Chem, Brighton BN1 9QJ, E Sussex, England

[2] Univ Durham, Dept Chem, South Rd, Durham DH1 3LE, England

[3] Victoria Univ Wellington, Sch Chem & Phys Sci, POB 600, Wellington 6012, New Zealand

来源：

INORGANIC CHEMISTRY | 2017年 / 56卷 / 24期

关键词：

X-RAY CRYSTAL; MOLECULAR-STRUCTURE; COORDINATION CHEMISTRY; MULTIPLE BONDS; MAIN-GROUP; SE; GERMANIUM; SN; TIN(II); TE;

D O I：

10.1021/acs.inorgchem.7b02040

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of tin and lead phosphanido complexes with chalogens is reported. The addition of sulfur to [(BDI)MPCy2] (M = Sn, Pb; BDI = CH{(CH3)CN-2,6-iPr(2)C(6)H(3)}(2)) results in the formation of phosphinodithioates [(BDI)MSP(S)Cy-2] regardless of the conditions; however, when selenium is added to [(BDI)MPCy2], a selenium insertion product, phosphinoselenoite [(BDI)MSePCy2], can be isolated. This compound readily reacts with additional selenium to form the phosphinodiselenoate complex [(BDI)MSeP(Se)Cy-2]. In contrast, the addition of selenium to [(BDI)SnP(SiMe3)(2)] results in the formation of the heavy ether [(BDI)SnSeSiMe3]. Differences in the solution and solid-state molecular species of tin phosphinoselenoite and phosphinodiselenoate complexes were probed :using multinudear solution and solid-state NMR spectroscopy.

引用

页码：14831 / 14841

页数：11

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