The atom-efficient cross-coupling of triarylbismuths with aryl iodides or aryl triflates using catalytic Pd(OAc)(2)/PPh3 and K3PO4 as base in DMF at 90 degrees C to afford the corresponding functionalized biaryls in high yields is reported. (c) 2007 Elsevier Ltd. All rights reserved.
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Fudan Univ, Dept Chem, Shanghai 200433, Peoples R ChinaFudan Univ, Dept Chem, Shanghai 200433, Peoples R China
Zhang, Liang
Qing, Jiang
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Fudan Univ, Dept Chem, Shanghai 200433, Peoples R ChinaFudan Univ, Dept Chem, Shanghai 200433, Peoples R China
Qing, Jiang
Yang, Pengyuan
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Fudan Univ, Dept Chem, Shanghai 200433, Peoples R ChinaFudan Univ, Dept Chem, Shanghai 200433, Peoples R China
Yang, Pengyuan
Wu, Jie
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Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R ChinaFudan Univ, Dept Chem, Shanghai 200433, Peoples R China