PALLADIUM-CATALYZED CYCLIZATION AND CROSS-COUPLING OF ACETYLENIC ARYL TRIFLATES WITH ORGANOTIN REAGENTS

被引：18

作者：

LUO, FT

WANG, RT

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang, Taipei

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 52期

关键词：

D O I：

10.1016/0040-4039(91)80570-V

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acetylenic aryl triflates reacted readily with vinyltributyltin, allyltributyltin, 1-(trimethylsilyl)-2-(tributylstannyl)-acetylene, and trimethylsilyltributyltin in the presence of a palladium catalyst to produce (Z)-indanylidene and (Z)-tetralinylidene substituted compounds, the stereospecificity of the reactions for the synthesis of these compounds being greater-than-or-equal-to 98%.

引用

页码：7703 / 7706

页数：4

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