Characterization of Cu2ZnSnSe4 solar cells prepared from electrochemically co-deposited Cu-Zn-Sn alloy

被引：28
|
作者：
Kondrotas, R. [1 ]
Juskenas, R. [1 ]
Naujokaitis, A. [1 ,2 ]
Selskis, A. [1 ]
Giraitis, R. [1 ]
Mockus, Z. [1 ]
Kanapeckait, S. [1 ]
Niaura, G. [1 ]
Xie, H. [3 ]
Sanchez, Y. [3 ]
Saucedo, E. [3 ]
机构：
[1] State Res Inst Ctr Phys Sci & Technol, Savanoriu Ave 231, Vilnius, Lithuania
[2] Vilnius Univ, Fac Phys, LT-10222 Vilnius, Lithuania
[3] IREC, Catalonia Inst Energy Res, Barcelona, Spain
来源：
SOLAR ENERGY MATERIALS AND SOLAR CELLS | 2015年 / 132卷
关键词：
CZTSe; Electrochemical co-deposition; Selenization; Solar cells; Cross-section; CZTS THIN-FILMS; STEP ELECTRODEPOSITION; COMPLEXING AGENT; ABSORBER LAYERS; SINGLE; SULFURIZATION; SELENIZATION; PRECURSORS;
D O I：
10.1016/j.solmat.2014.08.010
中图分类号：
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号：
0807 ; 0820 ;
摘要：
Cu-Zn-Sn (CZT) precursors for Cu2ZnSnSe4 (CZTSe) solar cell were prepared by electrochemical co-deposition method with different metals composition. CZT precursors were preliminary annealed in three different atmospheres in order to obtain homogenous, without pores Cu-Zn-Sn layers. A high crystalline quality CZTSe absorber was synthesised as has been determined by X-ray diffraction and Raman spectroscopy methods. CZTSe based solar cells were fabricated and champion cell demonstrated 2.7% efficiency and reached as high as 70% of external quantum efficiency. Scanning electron microscope investigations of CZTSe solar cells cross-section revealed that Mo/CZTSe interface exhibits large voids and local delamination from Mo layer. The back contact issues are detrimental to solar cell performance reducing shunt resistance and open circuit voltage. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：21 / 28
页数：8
相关论文
共 50 条
  • [41] Synthesis and characterization of Cu2ZnSnSe4 nanocrystals prepared by one pot route
    Wang, Tingting
    Chen, Qinmiao
    Chen, Jin
    Zhou, Fangfang
    Jia, Zhen
    Dou, Xiaoming
    Zhuang, Songlin
    CRYSTAL RESEARCH AND TECHNOLOGY, 2014, 49 (10) : 808 - 812
  • [42] Defect characterization in co-evaporated Cu2ZnSnSe4 thin film solar cell
    Kim, Yongshin
    Choi, In-Hwan
    CURRENT APPLIED PHYSICS, 2016, 16 (09) : 944 - 948
  • [43] Preparation of Cu2ZnSnSe4 thin films by selenization of precursor evaporated from Cu2ZnSnSe4 compound
    Yamaguchi, T.
    Kawamoto, K.
    Oura, S.
    Niiyama, S.
    Imanishi, T.
    PHYSICA STATUS SOLIDI C: CURRENT TOPICS IN SOLID STATE PHYSICS, VOL 10, NO 7-8, 2013, 10 (7-8): : 1071 - 1074
  • [44] Reaction Pathway for Efficient Cu2ZnSnSe4 Solar Cells from Alloyed Cu-Sn Precursor via a Cu-Rich Selenization Stage
    Pareek, Devendra
    Taskesen, Teoman
    Marquez, Jose A.
    Stange, Helena
    Levcenco, Sergiu
    Simsek, Ibrahim
    Nowak, David
    Pfeiffelmann, Timo
    Chen, Wenjian
    Stroth, Christiane
    Sayed, Mohamed H.
    Mikolajczak, Ulf
    Parisi, Juergen
    Unold, Thomas
    Mainz, Roland
    Guetay, Levent
    SOLAR RRL, 2020, 4 (06)
  • [45] Nanocrystalline Cu2ZnSnSe4 thin films for solar cells application: Microdiffraction and structural characterization
    Quiroz, Heiddy P.
    Dussan, A.
    JOURNAL OF APPLIED PHYSICS, 2016, 120 (05)
  • [46] Electrochemical Synthesis of CU2ZnSnS4 and CU2ZnSnSe4 Thin Films for Solar Cells
    Ikeda, Shigeru
    Septina, Witman
    Lin, Yixin
    Kyoraiseki, Akio
    Harada, Takashi
    Matsumura, Michio
    PROCEEDINGS OF 2013 INTERNATIONAL RENEWABLE AND SUSTAINABLE ENERGY CONFERENCE (IRSEC), 2013, : 1 - 4
  • [47] Achieving 11.95% efficient Cu2ZnSnSe4 solar cells fabricated by sputtering a Cu-Zn-Sn-Se quaternary compound target with a selenization process
    Li, Xinchen
    Zhuang, Daming
    Zhang, Ning
    Zhao, Ming
    Yu, Xinping
    Liu, Peng
    Wei, Yaowei
    Ren, Guoan
    JOURNAL OF MATERIALS CHEMISTRY A, 2019, 7 (16) : 9948 - 9957
  • [48] Zn-poor Cu2ZnSnSe4 thin films and solar cell devices
    Fairbrother, Andrew
    Neuschitzer, Markus
    Saucedo, Edgardo
    Perez-Rodriguez, Alejandro
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2015, 212 (01): : 109 - 115
  • [49] Modifying the Hetero-junction Interface of Cu2ZnSnSe4 Solar Cells
    Zhang, Yi
    Li, Jianjun
    Liu, Xiaoru
    Wu, Li
    Ao, Jianping
    Sun, Yun
    2018 IEEE 7TH WORLD CONFERENCE ON PHOTOVOLTAIC ENERGY CONVERSION (WCPEC) (A JOINT CONFERENCE OF 45TH IEEE PVSC, 28TH PVSEC & 34TH EU PVSEC), 2018, : 3059 - 3061
  • [50] Crystallization of kesterite Cu2ZnSnS4 prepared by the sulfurization of sputtered Cu-Zn-Sn precursors
    Amal, Muhamad I.
    Kim, Kyoo Ho
    Thin Solid Films, 2013, 535 (01) : 144 - 148
12345