Nonenzymatic Dynamic Kinetic Resolution of α-(Arylthio)- and α-(Alkylthio) alkanoic Acids

被引：46
|
作者：
Yang, Xing [1 ]
Birman, Vladimir B. [1 ]
机构：
[1] Washington Univ, Dept Chem, St Louis, MO 63130 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 24期
基金：
美国国家科学基金会;
关键词：
acyl-transfer catalysis; kinetic resolution; organocatalysis; racemization; synthetic methods; DUAL-FUNCTION CATALYSIS; ASYMMETRIC-SYNTHESIS; AMINO-ACIDS; ENZYMATIC RESOLUTION; ACHIRAL ALCOHOLS; CARBOXYLIC-ACIDS; ALPHA-ARYL; SULFENYLATION; DERIVATIVES; HOMOBENZOTETRAMISOLE;
D O I：
10.1002/anie.201007860
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dynamic solution: The title acids undergo dynamic kinetic resolution during an enantioselective esterification catalyzed by (S)-homobenzotetramisole ((S)-HBTM; see scheme). This method extends the scope of the carboxylic acid derivatives that are amenable to the nonenzymatic version of this transformation. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：5553 / 5555
页数：3
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