Nonenzymatic Acylative Kinetic Resolution of Racemic Amines and Related Compounds

被引：86
|
作者：
Krasnov, Victor P. [1 ]
Gruzdev, Dmitry A. [1 ]
Levit, Galina L. [1 ]
机构：
[1] RAS, Postovsky Inst Organ Synth, Ekaterinburg 620990, Russia
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 2012卷 / 08期
基金：
俄罗斯基础研究基金会;
关键词：
Kinetic resolution; Acylation; Amines; Amides; ENANTIOSELECTIVE ACYL TRANSFER; PLANAR-CHIRAL DERIVATIVES; BETA-HYDROXY AMINES; ENANTIOMERIC EXCESS; ABSOLUTE-CONFIGURATION; ASYMMETRIC-SYNTHESIS; SECONDARY ALCOHOLS; NUCLEOPHILIC CATALYSIS; SEC-ALCOHOLS; 1-SUBSTITUTED 3-AMINO-1,2-DICARBA-CLOSO-DODECABORANES;
D O I：
10.1002/ejoc.201101489
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Acylative kinetic resolution of racemic amines occupies a highly important place among the methods for preparation of enantio enriched or pure amines. Nonenzymatic acylative kinetic resolution is usually carried out in the presence of chiral acyl-transfer catalysts or under the action of chiral enantio- or diastereoselective resolving agents. Recently, this line of investigations has been rapidly developed and very interesting results of design and synthetic application of both new catalysts and chiral acylating agents have been obtained. This microreview summarizes the recent advances in this area.
引用
收藏
页码：1471 / 1493
页数：23
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