[BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure

被引：80
|
作者：
Lin, Yumei [1 ]
Dehnen, Stefanie [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 17期
关键词：
IONIC LIQUIDS; ELECTRONIC-PROPERTIES; CRYSTAL-STRUCTURES; SUPERTETRAHEDRAL CLUSTERS; RAMAN-SPECTRA; SULFIDE; CHALCOGENIDE; TERNARY; ZN; MN;
D O I：
10.1021/ic200697k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [K-4(H2O)(4)][SnSe4] with [BMIm][BF4] at 130-180 degrees C afforded [BMIm](4)[Sn9Se20] (1). The anion of the title compound represents a unique three-dimensional (3D) open framework, based on a variety of interconnectivity modes of Sn/Se units that lead to a system of six intersecting channels. 1 comprises the first example of a binary 3D open-framework selenidostannate anion and the first 3D open-framework chalcogenido metalate to be conveniently obtained by ion othermal synthesis.
引用
收藏
页码：7913 / 7915
页数：3
相关论文
共 50 条
  • [1] Synthesis and Modification of a Functionalized 3D Open-Framework Structure with MIL-53 Topology
    Ahnfeldt, Tim
    Gunzelmann, Daniel
    Loiseau, Thierry
    Hirsemann, Dunja
    Senker, Juergen
    Ferey, Gerard
    Stock, Norbert
    INORGANIC CHEMISTRY, 2009, 48 (07) : 3057 - 3064
  • [2] Ionothermal synthesis of a new open-framework zinc phosphite NIS-3 with low framework density
    Feng, Jing-Dong
    Shao, Kui-Zhan
    Tang, Shu-Wei
    Wang, Rong-Shun
    Su, Zhong-Min
    CRYSTENGCOMM, 2010, 12 (05): : 1401 - 1403
  • [3] Ternary 3D framework [Ag5Sn4Se12]3- : Solvothermal synthesis, crystal structure and photoelectric properties of an organic silver-rich selenidostannate hybrid
    Tian, Yiming
    Zhang, Jiahua
    Wang, Wenbao
    Jia, Dingxian
    INORGANIC CHEMISTRY COMMUNICATIONS, 2021, 131
  • [4] Hydrothermal Synthesis and Crystal Structure of a New 3-D Open-framework Zincophosphate
    陈雪焕
    曹彦宁
    张汉辉
    陈义平
    陈新香
    柴小川
    Chinese Journal of Structural Chemistry, 2008, (04) : 409 - 415
  • [5] Hydrothermal Synthesis and Crystal Structure of a New 3-D Open-framework Zincophosphate
    陈雪焕
    曹彦宁
    张汉辉
    陈义平
    陈新香
    柴小川
    结构化学, 2008, (04) : 409 - 415
  • [6] Hydrothermal synthesis and crystal structure of a new 3-d open-framework zincophosphate
    Chen Xue-Huan
    Cao Yan-Ning
    Zhang Han-Hui
    Chen Yi-Ping
    Chen Xin-Xiang
    Chai Xiao-Chuan
    CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2008, 27 (04) : 409 - 415
  • [7] Ionothermal Synthesis and Structure Analysis of an Open-Framework Zirconium Phosphate with a High CO2/CH4 Adsorption Ratio
    Liu, Lei
    Yang, Jiangfeng
    Li, Jinping
    Dong, Jinxiang
    Sisak, Dubravka
    Luzzatto, Marisa
    McCusker, Lynne B.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (35) : 8139 - 8142
  • [8] An open-framework bimetallic chalcogenide structure K3Rb3Zn4Sn3Se13 built on a unique [Zn49Sn3Se16] 12- cluster:: synthesis, crystal structure, ion exchange and optical properties
    Wu, M
    Sul, WP
    Jasutkar, N
    Huang, XY
    Li, J
    MATERIALS RESEARCH BULLETIN, 2005, 40 (01) : 21 - 27
  • [9] A new 3D nickel(II) framework composed of large rings: Ionothermal synthesis and crystal structure
    Xu, Ling
    Choi, Eun-Young
    Kwon, Young-Uk
    JOURNAL OF SOLID STATE CHEMISTRY, 2008, 181 (11) : 3185 - 3188
  • [10] A 3D open-framework indium telluride and its selenide and sulfide analogues
    Wang, C
    Bu, XH
    Zheng, NF
    Feng, PY
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2002, 41 (11) : 1959 - +
12345