[BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure

被引：80
|
作者：
Lin, Yumei [1 ]
Dehnen, Stefanie [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 17期
关键词：
IONIC LIQUIDS; ELECTRONIC-PROPERTIES; CRYSTAL-STRUCTURES; SUPERTETRAHEDRAL CLUSTERS; RAMAN-SPECTRA; SULFIDE; CHALCOGENIDE; TERNARY; ZN; MN;
D O I：
10.1021/ic200697k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [K-4(H2O)(4)][SnSe4] with [BMIm][BF4] at 130-180 degrees C afforded [BMIm](4)[Sn9Se20] (1). The anion of the title compound represents a unique three-dimensional (3D) open framework, based on a variety of interconnectivity modes of Sn/Se units that lead to a system of six intersecting channels. 1 comprises the first example of a binary 3D open-framework selenidostannate anion and the first 3D open-framework chalcogenido metalate to be conveniently obtained by ion othermal synthesis.
引用
收藏
页码：7913 / 7915
页数：3
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