[BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure

被引：80
|
作者：
Lin, Yumei [1 ]
Dehnen, Stefanie [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35043 Marburg, Germany
来源：
INORGANIC CHEMISTRY | 2011年 / 50卷 / 17期
关键词：
IONIC LIQUIDS; ELECTRONIC-PROPERTIES; CRYSTAL-STRUCTURES; SUPERTETRAHEDRAL CLUSTERS; RAMAN-SPECTRA; SULFIDE; CHALCOGENIDE; TERNARY; ZN; MN;
D O I：
10.1021/ic200697k
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [K-4(H2O)(4)][SnSe4] with [BMIm][BF4] at 130-180 degrees C afforded [BMIm](4)[Sn9Se20] (1). The anion of the title compound represents a unique three-dimensional (3D) open framework, based on a variety of interconnectivity modes of Sn/Se units that lead to a system of six intersecting channels. 1 comprises the first example of a binary 3D open-framework selenidostannate anion and the first 3D open-framework chalcogenido metalate to be conveniently obtained by ion othermal synthesis.
引用
收藏
页码：7913 / 7915
页数：3
相关论文
共 50 条
  • [21] The ionothermal synthesis of a 3D indium metal-organic framework: Crystal structure, photoluminescence property and photocatalytic activity
    Ji, Wen-Juan
    Zhai, Quan-Guo
    Li, Shu-Ni
    Jiang, Yu-Cheng
    Hu, Man-Cheng
    INORGANIC CHEMISTRY COMMUNICATIONS, 2012, 24 : 209 - 211
  • [22] Synthesis and structure determination of a 2D open-framework zincophosphate templated by cyclohexylamine molecules
    Trojette, B
    Hajem, AA
    Driss, A
    Jouini, T
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 1998, 28 (05) : 339 - 342
  • [23] Synthesis and structure determination of a 2D open-framework zincophosphate templated by cyclohexylamine molecules
    Basma Trojette
    Amen Allah Hajem
    Ahmed Driss
    Tahar Jouini
    Journal of Chemical Crystallography, 1998, 28 : 339 - 342
  • [24] Investigations of guest-modulated ordering temperatures in open-framework 3D porous magnets
    Stride, John A.
    Kurmoo, Mohammedally
    Wang, Zheming
    PHYSICA B-CONDENSED MATTER, 2006, 385 : 465 - 467
  • [25] Proton Conduction in Organically Templated 3D Open-Framework Vanadium-Nickel Pyrophosphate
    Zhang, Le
    Liu, Xinxin
    Sun, Xuejiao
    Jian, Juan
    Li, Guanghua
    Yuan, Hongming
    INORGANIC CHEMISTRY, 2019, 58 (07) : 4394 - 4398
  • [26] Pd17In4Se4, a Metal-Rich Palladium-Indium Selenide with an Open-Framework Structure
    Zakharova, Elena Yu.
    Churakov, Andrei V.
    Doert, Thomas
    Kuznetsov, Alexey N.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2013, 2013 (36) : 6164 - 6169
  • [27] Ionothermal Syntheses and Characterization of Open-framework Manganese Phosphites (NH4)2Mn3(HPO3)4 and Mn(HPO3)
    He Yongke
    Yan Yan
    Yang Fen
    Wu Junbiao
    Song Xiaowei
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2014, 35 (09): : 1859 - 1863
  • [28] Synthesis and characterization of three open-framework zinc phosphites with (3,4)-connected frameworks
    Kang, Maoping
    Luo, Daibing
    Luo, Xiuchao
    Lin, Zhien
    SOLID STATE SCIENCES, 2011, 13 (08) : 1473 - 1477
  • [29] PKU-10: A New 3D Open-Framework Germanate with 13-Ring Channels
    Su, Jie
    Wang, Yingxia
    Wang, Zheming
    Liao, Fuhui
    Lin, Jianhua
    INORGANIC CHEMISTRY, 2010, 49 (21) : 9765 - 9769
  • [30] The first ionothermal synthesis of a 3D ferroelectric metal-organic framework with colossal dielectric constant
    Ji, Wen-Juan
    Zhai, Quan-Guo
    Li, Shu-Ni
    Jiang, Yu-Cheng
    Hu, Man-Cheng
    CHEMICAL COMMUNICATIONS, 2011, 47 (13) : 3834 - 3836
12345