An open-framework bimetallic chalcogenide structure K3Rb3Zn4Sn3Se13 built on a unique [Zn49Sn3Se16] 12- cluster:: synthesis, crystal structure, ion exchange and optical properties

被引：32
|
作者：
Wu, M [1 ]
Sul, WP [1 ]
Jasutkar, N [1 ]
Huang, XY [1 ]
Li, J [1 ]
机构：
[1] Rutgers State Univ, Dept Chem & Chem Biol, Piscataway, NJ 08854 USA
来源：
MATERIALS RESEARCH BULLETIN | 2005年 / 40卷 / 01期
基金：
美国国家科学基金会;
关键词：
chalcogenides; semiconductors; chemical synthesis; x-ray diffraction; optical properties;
D O I：
10.1016/j.materresbull.2004.09.016
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Single crystals of K3Rb3Zn4Sn3Se13 were synthesized by solvothermal method. The building block in this structure is a [Zn4Sn3Se16](12-) cluster which consists of four ZnSe4 and three SnSe4 tetrahedra connected through corner-sharing of Se atoms. The 3D network contains intersecting channels running parallel to the crystallographic [2 1 1], [1-1-1] and [12-1] directions. The disordered K+ and R+ cations reside in these channels. Ion exchange of Cs+ with disordered Rb+/K+ ions in the structure showed a partial replacement of 15.8%. Optical diffuse reflectance experiments were carried out and gave a sharp absorption edge at 2.6 eV. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：21 / 27
页数：7
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