Speciation of metals in biomolecules by use of inductively coupled plasma mass spectrometry with low and high mass resolution

被引:0
|
作者
Jakubowski, N [1 ]
Thomas, C [1 ]
Klueppel, D [1 ]
Stuewer, D [1 ]
机构
[1] Inst Spektrochem & Angew Spektroskopie, D-44013 Dortmund, Germany
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中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Speciation and metabolization of platinum and selenium in biological systems was investigated by HPLC coupled to low and high resolution ICP-MS. Using size exclusion chromatography more than 90% of the Pt found in a grass sample was present in an inorganic fraction while the remaining 10% occurred in 4 different organic fractions. Selenium Was studied in sea-gull eggs by use of reversed-phase HPLC. Six separated Se-organic compounds were observed, the major compounds being selenocystine and selenocystamine.
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页码:M37 / M43
页数:7
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