Speciation of metals in biomolecules by use of inductively coupled plasma mass spectrometry with low and high mass resolution

被引:0
|
作者
Jakubowski, N [1 ]
Thomas, C [1 ]
Klueppel, D [1 ]
Stuewer, D [1 ]
机构
[1] Inst Spektrochem & Angew Spektroskopie, D-44013 Dortmund, Germany
关键词
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Speciation and metabolization of platinum and selenium in biological systems was investigated by HPLC coupled to low and high resolution ICP-MS. Using size exclusion chromatography more than 90% of the Pt found in a grass sample was present in an inorganic fraction while the remaining 10% occurred in 4 different organic fractions. Selenium Was studied in sea-gull eggs by use of reversed-phase HPLC. Six separated Se-organic compounds were observed, the major compounds being selenocystine and selenocystamine.
引用
收藏
页码:M37 / M43
页数:7
相关论文
共 50 条
  • [21] Inductively Coupled Plasma Mass Spectrometry
    Beauchemin, Diane
    ANALYTICAL CHEMISTRY, 2010, 82 (12) : 4786 - 4810
  • [23] Speciation of inorganic selenium by inductively coupled plasma mass spectrometry with hydraulic high pressure nebulization
    Jakubowski, N
    Thomas, C
    Stuewer, D
    Dettlaff, I
    Schram, J
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (11) : 1023 - 1029
  • [24] Speciation of inorganic selenium by inductively coupled plasma mass spectrometry with hydraulic high pressure nebulization
    Jakubowski, Norbert
    Thomas, Christoph
    Stuewer, Dietmar
    Dettlaff, Iris
    Schram, Juergen
    1996, Royal Soc of Chemistry, Cambridge, United Kingdom (11)
  • [25] Multielement analysis of whole blood by high resolution inductively coupled plasma mass spectrometry
    Rodushkin, I
    Ödman, F
    Branth, S
    FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1999, 364 (04): : 338 - 346
  • [26] Determination of Trace Elements in Wines by High Resolution Inductively Coupled Plasma Mass Spectrometry
    Fiket, Zeljka
    Mikac, Nevenka
    Kniewald, Goran
    ATOMIC SPECTROSCOPY, 2010, 31 (02) : 44 - 55
  • [27] PLASMA SOURCE-MASS SPECTROMETRY USING AN INDUCTIVELY COUPLED PLASMA AND A HIGH-RESOLUTION QUADRUPOLE MASS FILTER
    DATE, AR
    GRAY, AL
    ANALYST, 1981, 106 (1269) : 1255 - 1267
  • [28] Determination of metals in Brazilian soils by inductively coupled plasma mass spectrometry
    Rui M. de Carvalho
    Jéssica A. dos Santos
    Jessee A. S. Silva
    Thiago G. do Prado
    Adriel Ferreira da Fonseca
    Eduardo S. Chaves
    Vera L. A. Frescura
    Environmental Monitoring and Assessment, 2015, 187
  • [29] Inductively coupled plasma-mass spectrometry for the analysis of ancient metals
    Young, SMM
    Budd, P
    Haggerty, R
    Pollard, AM
    ARCHAEOMETRY, 1997, 39 : 379 - 392
  • [30] Uncertainty of high resolution inductively coupled plasma mass spectrometry based aerosol measurements
    Yenisoy-Karakas, Serpil
    Gaga, Eftade O.
    Cankur, Oktay
    Karakas, Duran
    TALANTA, 2009, 79 (05) : 1298 - 1305