Speciation of metals in biomolecules by use of inductively coupled plasma mass spectrometry with low and high mass resolution

被引:0
|
作者
Jakubowski, N [1 ]
Thomas, C [1 ]
Klueppel, D [1 ]
Stuewer, D [1 ]
机构
[1] Inst Spektrochem & Angew Spektroskopie, D-44013 Dortmund, Germany
关键词
D O I
暂无
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Speciation and metabolization of platinum and selenium in biological systems was investigated by HPLC coupled to low and high resolution ICP-MS. Using size exclusion chromatography more than 90% of the Pt found in a grass sample was present in an inorganic fraction while the remaining 10% occurred in 4 different organic fractions. Selenium Was studied in sea-gull eggs by use of reversed-phase HPLC. Six separated Se-organic compounds were observed, the major compounds being selenocystine and selenocystamine.
引用
收藏
页码:M37 / M43
页数:7
相关论文
共 50 条
  • [31] Determination of metals in Brazilian soils by inductively coupled plasma mass spectrometry
    de Carvalho, Rui M., Jr.
    dos Santos, Jessica A.
    Silva, Jessee A. S.
    do Prado, Thiago G.
    da Fonseca, Adriel Ferreira
    Chaves, Eduardo S.
    Frescura, Vera L. A.
    ENVIRONMENTAL MONITORING AND ASSESSMENT, 2015, 187 (08)
  • [32] Metals: common clinical applications in inductively coupled plasma mass spectrometry
    Cavey, Thibaud
    Ropert, Martine
    Loreal, Olivier
    Bendavid, Claude
    Peoc'h, Katell
    ANNALES DE BIOLOGIE CLINIQUE, 2019, 77 (05) : 495 - 504
  • [33] Selenium speciation analysis using inductively coupled plasma-mass spectrometry
    B'Hymer, C
    Caruso, JA
    JOURNAL OF CHROMATOGRAPHY A, 2006, 1114 (01) : 1 - 20
  • [34] Elemental speciation by chromatographic separation with inductively coupled plasma mass spectrometry detection
    de León, CAP
    Montes-Bayón, M
    Caruso, JA
    JOURNAL OF CHROMATOGRAPHY A, 2002, 974 (1-2) : 1 - 21
  • [35] Multielement analysis of whole blood by high resolution inductively coupled plasma mass spectrometry
    I. Rodushkin
    Fredrik Ödman
    Stefan Branth
    Fresenius' Journal of Analytical Chemistry, 1999, 364 : 338 - 346
  • [36] Speciation of mercury by capillary electrophoresis-inductively coupled plasma mass spectrometry
    Silva Da Rocha, M.
    Soldado, A.B.
    Blanco-González, E.
    Sanz-Medel, A.
    Biomedical Chromatography, 2000, 14 (01) : 6 - 7
  • [37] Speciation of halogenides and oxyhalogens by ion chromatography inductively coupled plasma mass spectrometry
    Pantsar-Kallio, M
    Manninen, PKG
    ANALYTICA CHIMICA ACTA, 1998, 360 (1-3) : 161 - 166
  • [38] Analysis of metals in condensates and naphtha by inductively coupled plasma mass spectrometry
    Olsen, SD
    Westerlund, S
    Visser, RG
    ANALYST, 1997, 122 (11) : 1229 - 1234
  • [39] Inductively coupled plasma mass spectrometry determination of metals in honeybee venom
    Kokot, Zenon J.
    Matysiak, Jan
    JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2008, 48 (03) : 955 - 959
  • [40] Nano-HPLC-inductively coupled plasma mass spectrometry for arsenic speciation
    Brennan, Ryan G.
    Murdock, Su-Ann E. O'Brien
    Farmand, Maryam
    Kahen, Kaveh
    Samii, Salar
    Gray, Jessica M.
    Montaser, Akbar
    JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 2007, 22 (09) : 1199 - 1205