Speciation and metabolization of platinum and selenium in biological systems was investigated by HPLC coupled to low and high resolution ICP-MS. Using size exclusion chromatography more than 90% of the Pt found in a grass sample was present in an inorganic fraction while the remaining 10% occurred in 4 different organic fractions. Selenium Was studied in sea-gull eggs by use of reversed-phase HPLC. Six separated Se-organic compounds were observed, the major compounds being selenocystine and selenocystamine.
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Dept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, SpainDept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, Spain
Silva Da Rocha, M.
Soldado, A.B.
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Dept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, SpainDept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, Spain
Soldado, A.B.
Blanco-González, E.
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Dept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, SpainDept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, Spain
Blanco-González, E.
Sanz-Medel, A.
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Dept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, SpainDept. of Phys. and Analyt. Chemistry, University of Oviedo, C/ Julián Clavería 8, 33006, Oviedo, Spain