Preparation of diarylamines by the addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes

被引：9

作者：

Yang, TL ^{[1
]}

Cho, BP ^{[1
]}

机构：

[1] Univ Rhode Isl, Coll Pharm, Dept Biomed Sci, Kingston, RI 02881 USA

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 40期

关键词：

aryllithium; diarylamine; nitroarene;

D O I：

10.1016/j.tetlet.2003.07.002

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The addition of 4-(N,N-dimethylamino)phenyllithium to nitroarenes in THF (-78degreesC) affords the corresponding diarylamines in one-pot and the reaction appears to be general in scope. A 'nitroso'-based mechanism is proposed for this novel nitroreductive N-arylation reaction. (C) 2003 Elsevier Ltd. All rights reserved.

引用

页码：7549 / 7552

页数：4

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